磁性fe3o4c核壳纳米粒子合成 组装和应用-synthesis, assembly and application of magnetic fe 3 o 4c core-shell nanoparticles.docx

ABSTRACTDriven by the promising applications in high-density magnetic data storage media, ferrofluids, and biomedicine, an important research effort has been directed towards the study on the synthesis of nanoscale magnetic materials. Moreover, ordered functional structures of magnetic nanomaterials have some brand-new properties resulted from the spatial orientation and arrangement of the building blocks and can be viewed as the foundation for the formation of novel miniaturized nanodevices. So research on the assembly of nanoscale magnetic materials is very important from the point of view of science and applications.The objective of this dissertation is to explore new avenue for the solution-based synthesis of nanoscale magnetic materials, investigate the relationship between their magnetic parameters and their structure (size and/or shape), and develop some simple and effective technologies for assembling the magnetic block buildings into highly ordered functional structures. The main parts of the results are summarized below:Magnetite nanoclusters with average size about 120 nm have been prepared and allowed to self-assemble into one-dimensional (1D) nanochain structure with the average length about 2 μm by a simple magnetic-field-induced (MFI) assembly approach (0.20 T). The constituent, phase, and morphology of these 1D nanochains have been characterized by X-ray diffraction and Transmission electron microscopy. Magnetic measurement reveals that these 1D nanochains are weakly ferromagnetic at room temperature. In this paper, we discuss the influence of magnetization time and strength of external magnetic field on the formation of 1D nanochains. We also shows that by changing the amount of hydrogen peroxide in starting materials, 1D nanochains with different interparticle spacing can be obtained. This 1D nanochain structure with different interparticle spacing would be an ideal system for the further study of magnetization properties of 1D ordered magnetic na