磁纳米颗粒负载的离子液体制备与催化不对称michael加成分析-preparation and catalytic asymmetric michael addition analysis of ionic liquids loaded with magnetic nanoparticles.docx

万方数据万方数据significant decrease in effect. The possible reaction mechanism was presented based on several references and our experiment.Above all, the cyclohexanediamine derivatives based nanoparticles supported chiral ionic liquid was prepared, and it showed high efficient in asymmetric Michael addition reaction. The basic additives can significantly improve reaction rate, and the catalyst can be recycled to reuse. The catalyst may get more extensive application through further work.KEY WORDS ： Ionic liquids, Asymmetric Michael addition, Magnetic nanoparticles, Recyclability目 录 HYPERLINK \l _bookmark0 第一章 绪论 ............................................................................................................. 1 HYPERLINK \l _bookmark1 1.1 离子液体的性质与特点 ............................................................................... 1 HYPERLINK \l _bookmark2 1.2 Michael 加成反应 1 HYPERLINK \l _bookmark3 1.3 离子液体在 Michael 加成中的应用进展 2 HYPERLINK \l _bookmark4 1.3.1 酸性离子液体..................................................................................... 2 HYPERLINK \l _bookmark5 1.3.2 碱性离子液体..................................................................................... 7 HYPERLINK \l _bookmark6 1.3.3 手性离子液体................................................................................... 15 HYPERLINK \l _bookmark7 1.4 本论文的研究目的和主要工作.................................................................. 23 HYPERLINK \l _bookmark8 1.4.1 研究目的........................................................................................... 23 HYPERLINK \l _bookmark9 1.4.2 主要工作........................................................................................... 23 HYPERLINK \l _bookmark10 第二章 催化剂制备及表征.................................................................................... 24 HYPERLINK \l _bookmark11 2.1 实验仪器 .................................................................................................... 24 HYPERLINK \l _bookmark12 2.2 实验试剂 ..................