燃料电池的电解水装置 膜电极、聚合物膜.docVIP

HYPERLINK /science?_ob=ArticleURL_udi=B6V3F-50X9S6W-3_user=8793841_coverDate=10%2F31%2F2010_alid=1495695555_rdoc=1_fmt=high_orig=search_origin=search_zone=rslt_list_item_cdi=5729_st=5_docanchor=_ct=259_acct=C000050221_version=1_urlVersion=0_userid=8793841md5=5fe6bb3ea111f3a97f8623searchtype=a Performance enhancement of membrane electrode assemblies with plasma etched polymer electrolyte membrane in PEM fuel cell?Hydrogen EnergyIn this work, a surface modified Nafion 212 membrane was fabricated by plasma etching in order to enhance the performance of a membrane electrode assembly (MEA) in a polymer electrolyte membrane fuel cell. Single-cell performance of MEA at 0.7?V was increased by about 19% with membrane that was etched for 10?min compared to that with untreated Nafion 212 membrane. The MEA with membrane etched for 20?min exhibited a current density of 1700?mA?cm?2 at 0.35?V, which was 8% higher than that of MEA with untreated membrane (1580?mA?cm?2). The performances of MEAs containing etched membranes were affected by complex factors such as the thickness and surface morphology of the membrane related to etching time. The structural changes and electrochemical properties of the MEAs with etched membranes were characterized by field emission scanning electron microscopy, Fourier transform-infrared spectrometry, electrochemical impedance spectroscopy, and cyclic voltammetry. HYPERLINK /science?_ob=ArticleURL_udi=B6V3F-50MMT12-2_user=8793841_coverDate=09%2F30%2F2010_alid=1495695555_rdoc=2_fmt=high_orig=search_origin=search_zone=rslt_list_item_cdi=5729_st=5_docanchor=_ct=259_acct=C000050221_version=1_urlVersion=0_userid=8793841md5=b039d771be44de9ad97135searchtype=a Effect of ionomer content and relative humidity on polymer electrolyte membrane fuel cell (PEMFC) performance of membrane-electrode assemblies (MEAs) prepared by decal transfer method??Membrane-electrode assemblies (MEAs) were fabricated by the decal transfer method with various Naf