铌合金表面ni-pal2o3复合涂层的制备与抗氧化性能研究-preparation and oxidation resistance of ni - pal2o3 composite coating on niobium alloy surface.docxVIP

两种元素组成，其中Ni含量为94.81wt%，P的含量为5.19wt%，为中磷镀层。XRD结果表明镀层呈非晶结构。镀层细小的胞状结构有效增大了Al2O3涂层与镀层接触的比表面积，改善了涂层与合金基体间的粘附力。4、研究表明Ni-P/Al2O3涂层比Al2O3涂层有更优异的抗氧化性能。高温氧化后涂层与基体结合良好，未出现裂纹和开裂现象。计算表明单一的Al2O3涂层中存在很大的应力，在温差为900℃时Al2O3涂层的内应力达到-3.7125GPa。Ni-P中间结合层的加入可有效减缓涂层的内应力，提高涂层与基体的结合。关键词：铌合金溶胶-凝胶法Al2O3涂层化学镀高温抗氧化性PreparationandOxidationResistanceofNi-P/Al2O3CoatingonNiobiumAlloyABSTRACTNiobiumandniobiumalloysarethemostpromisingcandidateasstructuralmaterialsusedinaerospaceengines,weaponspropeller,nuclearreactors,submersibleandgasturbines,duetohighmeltingpoint,lowdensity,goodmachiningpropertiesandexcellenthightemperaturemechanicalproperties.However,akeyproblemispooroxidationresistancefromtheformationofNbO,NbO2andNb2O5athightemperature,whichstronglyrestrictstheirapplicationswidely.Inordertoenhanceoxidationresistance,hightemperatureprotectivecoatingisalwayssuggestedtobepreparedontheNiobiumalloys.Inthispaper,Al2O3coatingwaspreparedontheNiobiumalloybySol-gelmethod,andelectrolessplatingwassandwichedintotheAl2O3coatingandNiobiumalloysubstratetoimprovetheinterfacialstrength.Thechemicalcomposition,phasescompositionandmicrostructureofthetwocoatings(Al2O3coatingandNi-P/Al2O3coating)beforeandafterthermalexposurewereanalyzedbymeansofdifferentialthermalanalysis(DTA),X-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andenergydispersivespectroscopy(EDS).Thefollowingconclusionscanbedrawn:1、Al2O3precursorsolutionwaspreparedbyaluminumisopropoxide,deionizedwaterandHNO3.Al2O3solutionwasstableandtransparent,andbecameAl(OH)3afterthreestepreaction,andeventuallyturnedintoboehmiteAlOOHsolution.Al2O3wasformedafterbeingcoatedandvacuumheattreatment.2、Al2O3coatingwaspreparedbySol-gelmethodonniobiumalloysurface.Thecoatingwascompact,coveredoverniobiumalloy.TherewerethreeprimaryintermediatephasesAl2O3,AlNi3andAlPO4aswellasthreesecondaryoxidephasesNbO,NbO2andNb2O5afterhigh-temperatureoxidation.OxidationmassgaincurvesshowedthatAl2O3coatingcouldeffectivelyimprovetheoxidationresistanceofNb-basedalloys.Withprolongingoxidationti