纳米feofe3o4协同微生物对pcb77的降解分析-degradation analysis of pc b77 by nano - fefaf e3 o4 synergistic microorganism.docxVIP

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纳米feofe3o4协同微生物对pcb77的降解分析-degradation analysis of pc b77 by nano - fefaf e3 o4 synergistic microorganism.docx

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纳米feofe3o4协同微生物对pcb77的降解分析-degradation analysis of pc b77 by nano - fefaf e3 o4 synergistic microorganism

IV IV dechlorination which could reach to a significant effect. The degradation of PCB77 by a combination nanoscale Fe0/Fe3O4 with microorganism was studied. As a result, the combination of nanoscale Fe0/Fe3O4 and microorganism could accelerate the dechlorination of PCB77 compared to the individual. The degradation rate could reach to 93.30% by a combination nanoscale Fe0 and microorganism. The combination mechanism between nanoscale Fe0/Fe3O4 and microorganism could be described as follows: The cathodic hydrogen which was produced during the degradation process could be used to energy source for the autotrophic growth of degrading bacterium. Biphenyl produced by a subsequent chemical reductive process with nano-Fe0and nano-Fe3O4 which was considered as carbon source for degrading bacterium. The results showed that the growth microorganism value of the combination mechanism was higher than the single. The degradation of PCB77 in soils by combined nanoscale Fe0/Fe3O4 with microorganism was studied. The results showed that the degradation of PCB77 in soils could be described by first-order kinetic equation. The degradation rates varied with different soils. The half-lives (t1/2) of PCB77 were 133.3 d、141.4 d and 147.4 d in red soil, vertisol and alfisol, respectively. When adding nanoscale Fe3O4 and the microorganism, the half-lives were 46.5 d、49.4 d and 43.9 d, respectively. When adding nanoscale Fe0 and the microorganism, the half-lives were 26.3 d、29.9 d and 31.8 d, respectively. The results suggested that the combination of nanoscale Fe0/Fe3O4 and microorganism could accelerate the degradation of PCB77 in soils, which might be an effective method for the cleanup of contaminated sites. Keywords ： Polychlorinated Biphenyls, biodegradation, nanoscale iron, reductive dechlorination, combination degradation PAGE PAGE 10 文献综述 1 多氯联苯性质及环境行为 1.1 多氯联苯的理化特征、应用及污染现状多氯联苯 (polychlorinated biphenyls，PCBs)是目前国际上关注的 12 种持久性有机污染物(persistent organic pollutants，POPs