水泥基材料抗tsa侵蚀性能及机理的分析-analysis of tsa corrosion resistance and mechanism of cement-based materials.docxVIP

同硫酸镁侵蚀液，浓度为5%时破坏性最强，而复盐5%硫酸镁+5%硫酸钠对试件侵蚀破坏性强于5%硫酸镁。⑦三乙醇胺、氯化钠早强剂可提升早期抗低温硫酸盐侵蚀能力，但侵蚀后期改善效果逐渐减弱，且由于氯化钠对石膏的溶解性等原因，前期改善效果较差。葡萄糖酸钠减缓了水泥水化程度，降低结构致密性，加速了侵蚀的发生。关键字：硫酸盐侵蚀，碳硫硅钙石，水泥基材料，矿物掺合料，侵蚀破坏IIAbstractThethaumasiteformofsulfateattackisaspecialformofsulfateattackexiststothaumasiteasdegenerationproducts,itoccurdincement-basedmateri-alwhenexposedtothelowertemperature,sulfates,carbonatesandexcessofwaterenvironmentalconditions.Comparedwiththetypeoftraditionalsulfateattack,whenthethaumasiteformofsulfateattacktocement-basedmaterials,therewasnoobviousswelling,cracking,butdirectlymakeC-S-Hgeldisintegratewhichisincementpaste,andcauseatransformationofcementintoamushwhichhasnostrength,non-bindingability.Itsdistructionandconcealmentleadssignificantriskstoconcretestructures.ThispaperreliesontheNationalNaturalScienceFoundationofChina,in5℃lowtemperatureenvironment,studysthecontentoflimestonepowder,mineraladmixture,curingsystem,theimpactofenvironmentalconditionsandadmixturesonTSAofcement-basedmaterials.ErosionproductswerebytestingmethodsofX-raydiffractionanalysisandFouriertransforminfraredspectroscopy,toexploreanti-corrosionpropertiesandmechanismofTSA.Theresultsshowthat:①Theextentofdegenerationincreasedwithanincreaseinlimestoneamount.thesurfaceofspecimenwithoutlimestonehasaslightpeeling,flakingpart,theperformanceofconventionalsulfateattack.Aslimestonepowdercontentis15%and30%,degenerationproductshowedthaumasite,andtheproductismai-nlythaumasite,whenthecontentoflimestoneis30%.②Slag,silicafumeandflyashcanimprovetheanti-corrosionpropertiesofcement-basedmaterials,Theeffectivesnessiscloselyrelatedtocontent;Met-akaolinhasaluminousphasecomposition,soitcanmakeTSAmoreserious.Underthesameconditions,theabilityofanti-corrosionindescendingorderasfollows:60%SL7.5%SF30%SL15%SF30%FA15%FAblank7.5%MK15%MK.Theeffectivenessofmixedaddedofmineraladmixtureisbetterthanthecorrespondingsingledopedadmixture.③Differentlevelsofashwithsamecontent,becausethedifferenceofco-mpositionandfineness,itexhibitdifferentant