四氟金属酞菁有机场效应材料的合成与性能分析-synthesis and properties analysis of organic field effect materials of tetrafluoro - metal phthalocyanines.docxVIP

donotdissolveinCH2Cl2andacetonitrile;CuPcF4wasappliedinorganicfield-effectdeviceanddisplayedn-channelperformance,indicatingthatCuPcF4canbeusedasn-typesemiconductormaterialinfield-effectdevice.Thefield-effectmobilityis0.014cm2/V·sandtheratioofswitched-currentis100.KeyWords:organicsemiconductormaterial,organicthinfilmtransistors,metaltetrafluorophthalocyanines,4-fluorophthalimide目录第一章文献综述..........................................................................................................11.1有机场效应晶体管简介.....................................................................................11.2有机薄膜晶体管的应用......................................................................................21.3有机半导体材料.................................................................................................41.3.1p型半导体材料41.3.2n型半导体材料71.3.3双极性半导体材料.......................................................................................91.4金属酞菁及含氟金属酞菁的合成.....................................................................91.4.1金属酞菁的合成方法...................................................................................91.4.2含氟金属酞菁的合成方法.........................................................................101.5论文的研究内容...............................................................................................11第二章4-氟邻苯二甲酰亚胺及四氟金属酞菁的合成与表征................................122.1实验方法...........................................................................................................122.1.1主要原料及试剂.........................................................................................122.1.2仪器与设备.................................................................................................142.1.34-氨基邻苯二甲酰亚胺的合成..................................................................142.1.44-氟硼酸重氮基邻苯二甲酰亚胺的合成..................................................152.1.54-氟邻苯二甲酰亚胺的合成......................................................................152.1.6四氟金属酞菁的合成.................................