四方相钽铌酸钾钠单晶的电光性能分析-electro-optic properties of tetragonal potassium sodium tantalum niobate single crystal.docxVIP

AbstractCrystallinematerialshavegoodlighttransmittance,meanwhiletheywillproduceaseriesofeffectsintheappliedelectricfield,suchaspiezoelectriceffect,electro-opticeffect,andphotorefractiveeffect.Thereforecrystalmaterialiswidelypreparedelectro-opticdeflectorandelectro-opticmodulatorinthefieldoflaserelectronictechnology.Ingeneral,thecrystallinematerialwithexcellentopticalpropertiesrequiresafewfeatures,forexample:(1)largerefractiveindex,gooduniformity;(2)largeelectro-opticcoefficient;(3)relativelyeasytoobtainlargesize,high-qualitycrystal;(4)strongopticaldamageresistanceability;(5)widetransparentbandoflightandgoodtransmittanceetal.Butitissmallamountoftheelectro-opticcrystalwhichcansimultaneouslysatisfytheabovetwocharacteristics.Currently,onlyKDP,lithiumniobate(LiNbO3)andtantalumpotassium(KTN)canbewidelyusedintheworld.Inthepast,mostattentionfocusonthequadraticelectro-opticeffect.Becauseofthedifficultyofobtainninghigh-qualityandlargesizeoftetragonalcrystal,papersonlinearelectro-opticcoefficientareseldomfound.Backinthesixtiesofthelastcentury,theyfoundthattheKTNcrystalhasgoodopticalproperties.SowetakeTa-dopedKNNcrystalsasaresearchobjectandsystematicallystudythecrystalgrowth,dielectric,piezoelectricandopticalproperties.UsingTSSGmethod,wehavegrowncompositionaluniformity,andhighqualitycrystalsofKNTNbyoptimizingthetemperaturefieldandtheprocessparameters.Weresearchthekeytechnologyandprocessesofcrystalgrowth,analyzethecrystalstructureandqualityandthesegregationpropertyofTaandNbinKNT-KNNsolutionsystem.Then,weprepareexperimentalsamplesafterannealing,orientating,cutting,polishing,platingelectrodehandle.ThestructuresofKNTNcrystalswerestudiedbyusingX-raypowderdiffractionmethod.Thecrystals’latticeparameterswerestudiedasafunctionofcrystalcomposition.WeusethebridgemethodtomeasurethecapacitanceofflatsampleKNTN,whichchangeswithvarioustemperatures,findthevalueofitsCurietemperature.WedeterminetherelationshipbetweenthecompositionandcrystalrelaxationwiththerevisedCurie-Weisslaw.Takinghysteresislo