双酰腙和缩氨基硫脲类受体分子的合成及其识别性能分析-synthesis and identification of diacylhydrazone and thiosemicarbazone receptor molecules.docxVIP

3.2实验部分........................................................................................................373.2.1试剂与溶剂..........................................................................................373.2.2测试与分析仪器..................................................................................373.2.3实验原理..............................................................................................383.3结果与讨论....................................................................................................403.3.1阳离子识别..........................................................................................40阳离子识别能力的检测............................................................40Hg2+抗干扰试验4UV-vis滴定曲线的测定4最低检测线的测定....................................................................433.3.2阴离子识别...........................................................................................4阴离子识别能力的检测.............................................................44CN-抗干扰试验45UV-vis滴定曲线的测定453.4识别机理的探讨.............................................................................................463.4应用性试验.....................................................................................................473.5结论................................................................................................................48第四章基于长链取代双酰腙的F-受体合成及其响应型凝胶的制备494.1引言................................................................................................................494.2实验部分........................................................................................................504.2.1受体分子L5的合成过程504.2.2试剂和溶剂..........................................................................................504.2.3测试及分析仪器..................................................................................504.2.4受体分子L5的合成与表征514.2.5UV-vis吸收光谱的测定514.2.6L5有机凝胶的制备514.3结果和讨论....................................................................................................514.3.1受体L5在DMSO溶液中的阴