石墨烯-pt@au多孔金复合薄膜的制备及其电催化应用分析-preparation and electrocatalysis application analysis of graphene - pt @ au porous gold composite film.docxVIP

AbstractOwingtotheuniquephysical,mechanicalandchemicalpropertiesofgraphene,Graphene-basedcompositesusuallyexhibitoutstandingperformanceasfunctionalmaterialsinmanyapplicationfields.However,veryfewresearchaboutgraphenepreparedbyvapordepositionasacatalyticsupporthasbeenreported.Soit’ssignificanttoexploretheeffectivegraphene-basedcatalystmaterials.Nanoporousgoldiswidelyusedinmanyareas,andespeciallyascatalystcarrierformethanoloxidationinfuelcells.Inthiswork,weinventanovelcatalystwhichiscomposedofgrapheneandplatinum-nanoporousgold.Comparedwithplatinum-nanoporousgold,itshowsgreatimprovementincatalyticproperty.Nanoporousgold(NPG)withlargesurfacemadefromthemembranematerialofgoldandsilveralloywhichisonly100nmthickbyasimpledealloyingmethod.Nanoporousgold(NPG)canbecatalystcarrierforplatinumnanoparticleswhichisusedintheCatalysisformethanoloxidation.Underdifferentdepositiontime,morphologiesofplatinumnanoporousgoldareObtained.XRDanalysisconfirmedthatplatinumparticleshavebeendepositedonnanoporousgold.Bycyclicvoltammetrywemeasuredthecatalyticeffectofplatinum.Andfoundtheoptimalsynthesisconditionsforcatalysis.Bychemicalvapordepositionmethod,wefabrecatedthreedifferentdegreesofdefectivegrapheme.Andbyscanningelectronmicroscopyandopticalmicroscopytocharacterizethemorphologyofgraphene.weclearlyseethedifferentdegreesofdefectsingraphene.Inordertodeterminetheextentofdefectsinthesethreekind.ofgraphene,Ramanspectroscopyisusedtoanalyze.Thecompositematerialswhicharemadeofplatinumnanoporousgoldandgraphenewasusedinthecatalysisforoxidationofmethanol.Wefoundthatthecatalyticeffectofthecompositewasgreatlyimprovedcomparedwiththeplatinumnanoporousgold.Itmustbeemphasizedthatthegraphenehereweusedhavemoderatedefects.Thisgraphenemoderatelyimprovedcatalysisofplatinumnanoporousgold.Toinvestigatehowthedefectsongrapheneaffectingthecatalysis,wepreparedthreedifferentlevelsofdefects.Theresultsshowedthattoomanyorfewdefectswerenotgoodatimprovingthecatalysisforoxidationofmethanol.Therefore,itisconcludedthatthegraphene