石墨tdi型聚氨酯弹性体的制备及性能分析-preparation and properties analysis of graphite tdi polyurethane elastomer.docx

PreparationandCharacterizationofGraphite/TDITypePolyurethaneElastomerABSTRACTPolyurethaneelastomerhasgoodelasticity,abrasiveresistance,oilresistance,radiationresistance,ozoneresistance,andbiocompatibility.Ithasbeenwidelyusedinbuildingenergysaving,tireindustry,foodpackaging,adhesive,medicalappliancesandwaterproofmaterials,etc.However,thepoorheatresistanceofPUElimitsitsapplicationindifferentfields.Therefore,improvingthemechanicalpropertiesandheatresistanceofpolyurethaneelastomerisbecomingthestudyingfocus.Ordinarily,therearetwomainwaystopreparehighperformancepolyurethaneelastomer:onewayisselectingrawmaterialsofnewstructuresanddesigningnewexperimentalplan;theotherisaddinginorganicparticleswithgoodstabilityandhighmechanicalpropertiestothesystemofpolyurethaneelastomer.Inthispaper,themolecularweightofpolyethylenetetrahydrofuranetherglycol(PTMG),thecontentofNCO%inprepolymers,chainextensionagenttypeandtheinfluencesofcoefficientofchainextenderonmechanicalpropertiesofTDI-80andTDI-100werestudiedindetail.TheoptimumPTMG/TDI-100matrixsystemwasdetermined.ThreedifferentkindsofPUEcompositeswerepreparedwithPUEasthematrixandgraphiteasthefillerbyinsitupolymerization.Andtheinfluenceofgraphiteparticlesize,couplingagenttypesandcontentofgraphiteonthepropertiesofgraphite/PUEwerestudied.Itsmicroscopicstructure,mechanicalpropertiesandheatresistanceweredelicatelyinvestigatedanddiscussedbyFourierinfrared(FT-IR),electronicscanningelectronmicroscopy(SEM),X-raydiffraction(XRD),thetensiletest,tearresistancetest,differentialscanningcalorimetry(DSC)andsoon.Theresultsshowedthatcomparedwiththeblanksample,overallperformanceofPUEreachedthetopwhenE-300,KH-560,graphite(500mesh)withloadingof15wt%werechosenasthechainextensionagent,couplingagentandfiller,respectively.Thetensilestrength,tearstrengthincreasedby28.2%and24.5%,respectively.Andthemeltingtemperatureincreased44℃.KeyWords:Polyurethaneelastomer,graphite,microscopicstructure,physicalandmechanicalproperties,heatresistance目录第一章绪论1.1聚氨酯弹性体..................