石墨烯及其al-20si基复合材料的制备与性能研究-preparation and properties of graphene and its al - 20si matrix composites.docxVIP

石墨铝基复合材料一样，起到自润滑的效果，降低材料摩擦磨损系数。关键词:金属基复合材料；石墨烯；铝基复合材料；纳米材料；力学性能-II-AbstractThispaperisbasedontheactualapplicationofelectronicpackagingmaterials.Graphenealuminummatrixcomposite,includinggraphemeandAl-20Si,wasmadebytheballmillingandpressureinfiltrationprocess.Therawgraphenepreparedandgraphenereinforcedaluminummatrixcompositewasanalyzedandcharacterizedbyscanningelectronmicroscopy,XRD,transmissionelectronmicroscopy,atomicforcemicroscopy,infraredspectroscopy,Ramanspectroscopyandotherdetectionmethods.Theelectronictensiletestingmachine,thermalexpansionanalyzer,thermalconductivitytester,frictionandweartesterandotherequipmentwereusedtotesttheperformanceofgrapheme/Al-20Sicomposites.Withhighheatconductinggraphiteasrawmaterials,expandedgraphitecanbepreparedtosynthesisgraphenematerialsbytheimprovedHummersmethod.Preparedwithoutultrasonic,orshortultrasound,thelayerscanbepeeled.ThelayerofGraphenewasthin,justwithin1~10;thethicknessofgraphenepreparedwasbetween0.34~3nm;thegraphemepreparedwithoutotheroxygencontainingfunctionalgroupsalsohadahighdegreeofgraphitization.ComparedwithAl-20Sialloy,thepropertiesofthecompositeweregreatlyenhancedandimproved.Theelasticmodulusofthecompositeincreasedwithincreasingofgraphene,whichwasapproximatelylinearly,matchingthemixingrule.Thebendingstrengthandtensilestrengthincreasedfirstlyandthendecreasedwiththeincreasingofgraphenecontent,suchaswhengraphitecontentwas3vol.%,thebendingstrengthandtensilestrengthreachedthehighest,respectively617MPaand363MPa.ComparedtothematrixAl-20Si,thereasonwhythestrengthandplasticityincreasedwasdifferent.TheductilityofAl-20Siimproved,mainlybecauseofthatthegraphene,withhugespecificsurfaceareaandsurfacefolds,candeformwhilecompositematerialdeforms.Thedispersionofgraphene,knownasnano-size,showedadispersionstrengtheningeffect,whichimpededthemotionofdislocations.Meanwhilethegraphenecouldplaytheroleasbearloadsincompositematerials.Theability,resistancetohightemperaturecompression,improvewiththeadditionofgraphene.Thecoefficientofthermale