退火气氛对的电化学性质的影响RuO2 nano-oxides即时合成的方法：（Effect of the annealing atmosphere on the electrochemical properties of RuO2 nano-oxides synthesized by the Instant Method）.pdfVIP

Applied Catalysis B: Environmental 218 (2017) 385–397 Contents lists available at ScienceDirect Applied Catalysis B: Environmental j o u r na l h o m e p ag e: w w w. elsev /locate/apc atb Effect of the annealing atmosphere on the electrochemical properties of RuO2 nano-oxides synthesized by the Instant Method T. Audichon a,∗ , B. Guenot a,b , S. Baranton a , M. Cretin b , C. Lamy b , C. Coutanceau a,∗ a Université de Poitiers, IC2MP, UMR CNRS 7285, “Catalysis and Non-Conventional Media” Group, 4 Rue Michel Brunet, TSA 51106, 86073 Poitiers Cedex 9, France b ◦ Université de Montpellier, Institut Européen des Membranes, UMR ENSCM, UM, CNRS n 5635, 2 Place Eugène Bataillon, CC047, 34095 Montpellier Cedex 5, France a r t i c l e i n f o a b s t r a c t Article history: Ruthenium oxide materials have been synthesized by an “Instant method” assisted by microwave irradi- Received 18 April 2017 ation. The “as-synthesized” material has been annealed at different temperatures from 200 ◦ C to 450 ◦ C, Received in revised form 13 June 2017 under different atmospheres, air and nitrogen. The different samples were characterized by X-ray diffrac- Accepted 26 June 2017 tion, transmission electron microscopy and cyclic voltammetry (capacitance, charges involved, etc.). The Available online 29 June 2017 physicochemical and electrochemical characterizations have evidenced that the main effect of the anneal-