梯度ruxir1-xo2涂层钛阳极制备及在电合成n2o5中应用-preparation of gradient ru xir 1 - xo2 coated titanium anode and its application in electrosynthesis of n2o5.docxVIP
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梯度ruxir1-xo2涂层钛阳极制备及在电合成n2o5中应用-preparation of gradient ru xir 1 - xo2 coated titanium anode and its application in electrosynthesis of n2o5
Atlast,thereasonsfordeactivationwereanalysised.ThedeactivationofgradientcoatinganodeswithRuO2asinnermostlayerwasmainlycausedbymechanicallossofcatalystlayeranddissolutionofactivecomponent.ThedeactivationofgradientcoatinganodeswithIrO2asinnermostlayerwasmainlycausedbyanodicoxidationofTibase.However,thedeactivationofRu0.5Ir0.5O2/TiwasmainlyduetotheformationofinsulatingTiO2betweenthesurfaceofTibaseandtheactivecoating,andmechanicallossofthecoatingalsoaffectedthelifetime.KEYWORDS:gradientcoatinganode,organicadditives,electrocatalysis,dinitrogenpentoxide,electrochemicalstability目录前言..............................................................................................................................1第一章文献综述..........................................................................................................21.1电合成N2O5法概述21.2电合成N2O5用电极材料的研究进展21.3钛基涂层阳极的制备......................................................................................41.3.1热分解法................................................................................................41.3.2溶胶-凝胶法..........................................................................................51.3.3电沉积法................................................................................................51.3.4磁控溅射法............................................................................................61.4电极性能的影响因素......................................................................................61.4.1涂层组成的影响....................................................................................61.4.2涂液溶剂体系的影响............................................................................61.4.3热氧化温度的影响................................................................................71.4.4活性组分涂覆量的影响........................................................................71.4.5有机添加剂的影响................................................................................81.5钛基涂层阳极的失效原因及稳定性提高措施.........................................
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