微纳结构银粉的制备及其催化性能分析-preparation of silver powder with micro-nano structure and analysis of its catalytic performance.docxVIP

浓度为0.21M条件下所得的微纳结构银粉催化性能最好，其表观速率常数Kapp可以达到9.68×10-3s-1，该数值比文献中报道的纳米银的催化性能高10倍，并且比分散剂保护制备的微纳银粉具有更高的催化活性。通过分析结晶度和比表面积对催化性能的影响，发现结晶度对银粉的催化性能有决定性作用。关键词：微纳结构;银粉;形貌;抗坏血酸;催化剂AbstractUniformmicro/nano-structuredsilverparticleshaveattractedextensiveattentionduetotheirimportanceinawiderangeofapplicationsincludingelectronics,catalysis,optics,andsurface-enhancedRamanscattering(SERS).Theseapplicationsareduetotheuniquepropertiesofsilverparticles,whichmainlydependonthemorphologyandsizeofsilverparticles.Themorphologyandsizeofas-obtainedparticlesareaffectedbysynthesismethodsandconditions.Asaresult,interestinthesynthesisofmicro/nano-structuredsilverparticleshasbeengrowingsteadilyoverthepastdecades.Amongmanysynthesismethods,wetchemicalreductionmethodisprobablythemostpopularoneforitssimplicity,lowcostandeasinessofmanipulating.Therefore,wetchemicalreductionmethodwasusedtosynthesizemicro/nano-structuredsilverparticleswithdifferentmorphologiesandsizesinthiswork.Controlledsynthesisofsilverparticleswasinvestigatedbyreducingsilvernitratewithascorbicacid.Wesynthesizednotonlymono-dispersivesilverparticleswithdispersingagents,suchaspolyvinylpyrrolidone(PVP,K30)andgumarabic,butalsocleansilverparticleswithoutdispersingagents.ThestructureandmorphologyoftheseparticleswereinvestigatedbyX-raydiffraction(XRD),?eld-emissionscanningelectronmicroscopy(FESEM)andtransmissionelectronmicroscopy(TEM).Theinfluencefactors,suchasreactantconcentrations,reactiontimeandtemperaturewereinvestigated.Thecatalyticactivityofthesemicro/nano-structuredsilverparticleswastestedbycatalyticreductionofp-nitrophenolbysodiumborohydride.Thisworkmainlyincludesthefollowingaspects:PVPandgumarabicwereusedasdispersingagentstosynthesizesilverparticles,respectively.Itwasfoundthatthereactantconcentrationsandreaction,theaddingmethodofgumarabicandreactiontemperatureallhaveimportantinfluencesonthemorphologyandsizeofsilverparticles.Adjustingtheseparameters,mono-dispersivesilverparticlescouldbecontrollablysynthesized.Thecatalyticactivityofthes