稀土离子掺杂yvo4纳米发光材料的制备及性能分析-preparation and performance analysis of rare earth ion doped yvo 4 nano luminescent material.docx

ABSTRACT  PAGE 6 ABSTRACT Rare earth ion doped YVO4 luminescence nanomaterials have received extensive attention because of their good physical and chemical stability, excellent luminescence properties and high efficiency of absorption to ultraviolet light. Thus, study on preparation and luminescence properties of rare earth ion doped YVO4 luminescence nanomaterials is of important significance and application value. The research object of this paper was rare earth ion doped YVO4 luminescence nanomaterials, in which the doped rare earth ions mainly included Eu3+, Tm3+ and Dy3+ ions. This thesis used a novel facile method, the ion exchange method, to prepare rare earth ion doped YVO4 luminescence nanomaterials. YVO4 nanocrystals prepared using the ion exchange method had rare earth ions mostly located on their surfaces. These rare earth ions could more easily coordinate with organic ligands to form inorganic–organic hybrid materials. In this thesis, X-ray diffraction (XRD), photoluminescence (PL) spectra, transmission electron microscope (TEM), ultraviolet-visible (UV-Vis) absorption spectra, Fourier transform infrared (FTIR) spectroscopy, ultraviolet analyzer and other characterization methods were used to analyze and characterize the crystal structures, micromorphology and grain size, chemical properties and luminescence properties of the rare earth ion doped YVO4 luminescence nanomaterials. This thesis includes the following parts. The solvothermal method was used to synthesize YVO4 nanocrystals, which were used to form YVO4:Eu3+ nanocrystals using the ion exchange method. 2-Thenoyltrifluoroacetone (TTA) ligands were introduced to form the YVO4:Eu3+–TTA inorganic–organic hybrid nanostructures. TTA has strong sensitization effect on the YVO4:Eu3+ nanocrystals. It was found that the YVO4:Eu3+–TTA inorganic–organic hybrid nanostructures exhibited strong luminescence. The luminescence intensity of YVO4:Eu3+–0.1 mmol TTA hybrid nanostructures was the strongest, and