纤维素接枝共聚的机理和力学性能分析-mechanism and mechanical properties analysis of cellulose graft copolymerization.docxVIP

太原 太原理工大学硕士研究生学位论文 太原 太原理工大学硕 士研究生学位论文 PAGE PAGE III PAGE PAGE VI 如1ECHANISM AND MECHANICAL PROPERTIES OF CELLULOSE GRAFT COPOLYMERS ABSTRACT Cellulose is the most important skeletal component in plants and the most abundant renewable material in nature. Recently，owing to the rapid increase in petroleum price and the compelling requirement of sustainable development ， biodegradable and environmentally friendly cellulose materials have become a main topics of research and development. However，the application of cellulose materials is restricted by the some properties such as insolubility in general solvents，poor chemical resistance，and low strength，which are attributed to the structure of cellulose. Thus，the modification of the cellulose materials is required . The grafting reaction of cellulose has been the focus of the research of this kind. A large number of hydroxyl groups in cellulose macromolecules attribute to chemical modification of cellulose，thereby obtaining the cellulose materials with bifunctional properties and various chemical structure for different proposes. Therefore，the application of cellulose materials is broadened. The copolymerizat ion of caprolactam(CPL) onto cellulose usi ng potassium persu lfate and ammonium persulfate as reaction initiator was studied. The molecu lar structure，appearance，crystallinity，therrnal stability and mechanical properties of graft cellulose were characterized using infrared spectrometer， scanning electron microscope ，X-ray diffractometer，therrno gravimetric analyzer and electronic universal testing machine. The effects of various reaction parameters on grafting ratio，such as mass of monomer ，concentration of initiator，reaction time and reaction tempera阳re were evaluated. The main conclusions are as follows: NaOH，urea，thiourea and water were mixed in a ratio of 4:4:4:38.5(w/w)，as the available solvent of cellulose. And the optimum temperature to swell cel1ulo