(Sr,Ca)2MgSi2O7Eu2+,Dy3+长余辉发光材料及其在静电纺丝中的应用材料科学与工程专业论文.docxVIP

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(Sr,Ca)2MgSi2O7Eu2+,Dy3+长余辉发光材料及其在静电纺丝中的应用材料科学与工程专业论文.docx

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(Sr,Ca)2MgSi2O7Eu2,Dy3长余辉发光材料及其在静电纺丝中的应用材料科学与工程专业论文

II II (Sr, Ca)2MgSi2O7:Eu2+,Dy3+长余辉发光材料及其在静电纺丝中的应用英文摘要 (Sr, Ca)2MgSi2O7:Eu2+,Dy3+ long-persistent luminescence materials and their applications in electrospinning Abstract (Sr, Ca)2MgSi2O7:Eu2+,Dy3+ are two afterglow performance outstanding silicate long persistence luminescence materials, which have incomparable advantages of chemical stability compare with other long persistence luminescence materials. With the development of nanotechnology and biomedical, rare earth metals doped alkaline-earth metal silicate long persistence luminescence materials represents a rapidly expanding field such as biological probe, cell targeted tag and medical imaging. In this paper, for the first time, we have tried to mix the (Sr, Ca)2MgSi2O7:Eu2+,Dy3+ long persistent luminescence particles with polymer, and fabricate them into a new superfine composite fierbs by electrospinning. Also, properties of that have been characterized. Firstly, (Sr,Ca)2MgSi2O7:Eu2+,Dy3+ particles were synthesized by sol-gel method. Then, the results of characterization show that two kinds of crystal respectively can be indexed to PDF card no.75-1736 (Sr2MgSi2O7) and no.35-0592 (Ca2MgSi2O7). Two samples were respectively detected emission peak at 468 nm and 452 nm/537 nm. They rapidly decay in 200s and 100s after removing excitation and slowly decay in 400s and 200s, respectively. For Sr2MgSi2O7:Eu2+,Dy3+ particles, we have analyzed some factors which may affect the performance of their fluorescence and long afterglow, such as different synthesis methods, different Eu2+ and Dy3+ doping amount, different Eu2+/Dy3+ doping ratio and immersion environment. Results showed that the fluorescent performance and afterglow synthesized by sol-gel are better than that synthesized by solid phase method. Fluorescence emission intensity mainly depends on the content of Eu2+. Afterglow initial brightness and decay trend mainly depends on the content of Dy3+. The optimal doping ratio of Eu2+/Dy3+ is 1:2, also we verified