SPR传感器系统的分析及应用-测试计量技术及仪器专业论文.docxVIP

南京航空航天大学硕士学位论文 南京航空航天大学硕士学位论文 SPR SPR 传感器系统的研究与应用 I I II II 摘 要 表面等离子体波共振效应(Surface Plasmon Resonance)是一种发生在环境介质与金属膜 分界面的物理光学现象，而 SPR 传感器是基于该效应的一种新型传感器，通过检测物质折 射率的改变检测物质性能的改变。因其灵敏度高、响应速度快、抗干扰能力强等优点，被广 泛的应用到生物化学检测、食品工程检测、环境监测、土木结构和工程物理等多个领域，并 发挥着巨大的作用。本文分为以下几个部分展开： 首先，简单介绍了 SPR 效应的基本原理，文中以金属包层型对称三层平板波导为模型， 分析光波在波导中传输时，激发 SPR 效应模式变化及不同波长对应的光强变化。并利用 Optiwave 软件对 SPR 效应激发时各模式的光场强度及坡印亭矢量等参量进行模拟仿真分析。 其次，对内置调制层的棱镜型 SPR 传感器进行研究，从理论上分析了影响其性能的各 种因素。在此基础上设计出一种新型的串联分布式棱镜 SPR 传感器，分析其所具有的优势， 并对各种影响其精度的因素进行仿真，确定出最优膜层的种类和厚度，根据此参数对其进行 试验验证。 再次，利用光纤 SPR 传感器检测超声，分析超声及外界环境介质的参数与反射光谱之 间的关系，提出了一种新型超声在线实时监测法。 最后，根据 SPR 传感器的共振波长会随金属膜层外界介质的折射率改变而改变的原理， 设计出一种 SPR 化学传感器。将其应用到医药废水降解在线监测中，为 SPR 传感器在污水 降解检测上的应用提供基础研究。 关键词：表面等离子体共振，波导理论，棱镜 SPR 传感器，光纤 SPR 传感器，超声检测， 化学检测 ABSTRACT Surface plasmon resonance effect is a quantum optical-electrical phenomenon which arises from the interaction between light with metals surface，and SPR sensor is a novel sensor based on this effect, which studies the property of environment outside the metals surface by refractive index measure. For its high sensitivity, low response time, strong capacity of resisting disturbance, suitable for remote telemetering, it has been widely used in many areas, such as biochemistry detection, food engineering detection, environmental monitoring, civil structure and engineering physics, and plays a tremendous role. This paper will be divided into the following several parts: Firstly, the basic principle of SPR effect is introduced briefly, when waves propagate in waveguide, how SPR effect influence the change of pattern and different wavelengths light intensity are analyzed, which based on the model of metal-coated stratotype symmetrical three layers of planar wave-guide. And Optiwave is used to emulate the modes of light field intensity and Poynting vector when the SPR effect is excited. Secondly, the multi-modulation layer prism SPR sensor is discussed in this paper. The factors which affect SPR spectra are analyzed. Making a