中空sn-nialloy@peo锂离子电池负极制备和性能研究-preparation and properties of hollow sn - ni alloy @ peo lithium ion battery cathode.docxVIP

下载本文档

5
0
约7.33万字
约 73页
2018-09-10 发布于上海
举报
版权申诉

中空sn-nialloy@peo锂离子电池负极制备和性能研究-preparation and properties of hollow sn - ni alloy @ peo lithium ion battery cathode.docx

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

中空sn-nialloy@peo锂离子电池负极制备和性能研究-preparation and properties of hollow sn - ni alloy @ peo lithium ion battery cathode

ABSTRACT The urgent need for the development of an new generation of high-performance lithium-ion batteries is searching for novel anode materials for lithium-ion batteries with high capacity. However, a great deal of negative-electrode materials with high capacity,such as Si-based, Sn-based, Ge-based and graphite,suffer from serious volume expansion and generate mechanical stress during the alloying/dealloying process,which leads to the pulverization of the active materials and thus the poor electrochemical performance. Three-dimensional Sn-Ni alloy is of great significance for the development of high-capacity and high-power lithium-ion battery. However, the application is limited by the poor stability of 3D nanostructure and large volume change during the alloying process. In this paper, we designed and prepared Sn-Ni alloy hollow nanoparticles (Sn-Ni alloy HNPs) and Sn-Ni alloy nanotubes (Sn-Ni alloy NTs) as anodes for lithium-ion batteries by galvanic replacement reaction and coating polymer membrane. Scanning electron microscope (SEM), Transmission electron microscopy (TEM) and X-ray diffraction (XRD) were used to measure the morphology, structure and composition of the samples,and then confirm the formation of hollow structure and the successful coating of polymer. In contrast with bare Sn-Ni alloy HNPs, PEO coated Sn-Ni alloy HNPs （ Sn-Ni alloy@PEO membrane HNPs ） exhibits better electrochemical performance, with a capacity of 506.6 mAhg-1 over 50 cycles, but without coating of the Sn-Ni alloy HNPs capacity only 300 mAhg-1, about improved 200mAhg-1; Compared with Sn-Ni alloy NTs without coating, Sn-Ni alloy@PEO membrane NTs shows better electrochemical characteritics, maintaining a capacity of 0.88 mAhcm-2 over 200 cycles, without coating Sn-Ni alloy NTs only 0.6 mAhcm-2, improved 0.28 mAhcm-2. Its good electrochemical performance is due to the hollow nanostructure and flexible polymer shells which relieves the volume change during the charging and dischargin