组合物化工艺处理高含盐采气废水分析-analysis of combined physicochemical process for treatment of high salinity gas production wastewater.docxVIP

西南科技大学环境工程硕士专业学位论文第 西南科技大学环境工程硕士专业学位论文 第 PAGE II 页 西南科技大学环境工程硕士专业学位论文第 西南科技大学环境工程硕士专业学位论文 第 PAGE III 页 Abstract High salinity gas production wastewater with high content of oils and COD, high mineralization and difficultly biochemical was utilized to wastewater treatment in this object. It was difficult to satisfy the discharge standard after using a single process or biological method. Thence, the variety of methods was used in combination to form a new treatment technology and meet the rule of reduction, which was a new trend with certain of practical significance. This paper mainly studied the feasibility of combined process of acid analysis-Fenton-activated carbon adsorption which was used to deal with the gas production wastewater, and investigated the concrete reaction conditions which could impact each step of treatment and the corresponding contamination indicators, and defined the optimal reaction conditions of the ultimate combination of technology. First of all, the gas production wastewater was tested with acid analysis. The removal efficiency of SS, oil substance, chromaticity, COD could reach 91%, 30%, 32% and 27% respectively and we could get the more effective oil-water separation at the pH of 1. Secondly, we defined the preliminary operating conditions of Fenton via orthogonal experiments, and the main factors affecting the removal efficiency of COD were researched individually via single factor analysis. The study results showed that the optimal operating condition of the Fenton: H2O2/COD was 7, H2O2/Fe2+ (molar ratio) was 3, the value of pH was 1, the time of reaction was 120min, and the removal efficiency of COD, SS, the oil substance, chromaticity could reach 64%, 97%, 89%, 93%, and the effluent was clear and significant after treated. The wastewater oxidized by the Fenton was treated via the activated carbon adsorption. We researched the influence of the different dosage and adsorption time on the COD removal efficiency in the adsorption e