《基于联苯三甲酸的LnBPT的制备与发光性能研究.docxVIP

PAGE \* MERGEFORMATII 基于联苯三甲酸的LnBPT的制备与发光性能研究 摘要 金属有机框架材料(Metal-Organic Frameworks简称MOFs)是以有机配体为桥链，金属离子或金属团簇为中心,金属离子与有机配体通过配位键相互构建成高度结晶化的网状骨架，从而形成的一种有机－无机框架材料，其具有的微观拓扑结构多变，在性质上也有着磁、光、电、催化及吸附等多方面优异性能，因其光学性能优良，在荧光与荧光探测、微粒识别、成像乃至生物标记等领域均有着极具研究前景的开发和应用价值。本文通过三种稀土离子混合的方式，选用能量传递效率良好的H3BPT(联苯三甲酸)为有机配体，采用水热溶剂法，先后制备出四种不同比例的多稀土MOFs材料，同时先制备出三种稀土离子的单稀土MOFs材料，铕、铽双稀土离子MOFs荧光材料作为后期对比，探究了La3+掺入铕、铽双稀土离子黄色荧光材料后对配合物的晶体结构，Eu3+、Tb3+ 两种稀土离子发光性能的影响，结果显示：（1）单稀土离子MOFs材料形成了同构配合物，LaBPT在380nm有蓝光发射峰，EuBPT发射红光、TbBPT 发射绿光（2）三稀土离子混合MOFs材料仍然为一种同构配合物，与单稀土MOFs材料晶体结构相近，增加La3+离子的用量比例，样品开始由黄光区蓝移，同时绿光发射增强（3）综合实验结果，镧离子都在一定程度上敏化了两种稀土离子发光，对铽离子的敏化效果比较明显，镧离子用量随比例增大，有机配体的蓝光发射有小幅度增强。 关键词：多稀土离子；H3BPT；晶体结构；发光性能  Preparation and luminescence properties of LnBPT based on biphenyl three carboxylic acid. Abstract: Metal Organic framework materials (Metal - Organic Frameworks MOFs) is based on Organic ligand bridge chains, Metal ions or Metal clusters as the center, Metal ions and Organic ligands by coordination bond mutual build into highly crystal mesh skeleton, thus forming a kind of Organic - inorganic framework material, its microscopic topology and changeful, also has the magnetic in nature, light, electricity, adsorption and catalytic aspects of excellent performance, due to its excellent optical performance, In fluorescence and fluorescence detection, particle identification, imaging and even biomarkers, it has great research prospects and application value. In this paper, we choose the energy transfer efficiency good H3BPT three formate (PCB) as organic ligands, three kinds of rare earth ions,use the hydrothermal solvent method. We have prepared four kinds of different proportions of rare earth fluorescent material, at the same time, the preparation of the first three single rare earth fluorescent MOFs materials of rare earth ions, double rare earth europium, terbium ion MOFs fluorescent material late as contrast, explores the La3 + doped europium and terbium rare earth ion after yellow fluorescence mate