背部球型ag纳米粒子对提高硅薄膜太阳能电池光吸收特性的研究-光学专业论文.docxVIP

摘 要 现如今金属纳米粒子在太阳能电池中单晶硅薄膜太阳能电池的应用越来越广泛， 利用这种新型的电池结构，金属纳米粒子增强等离子体的局域共振效应，因为利用金 属纳米粒子作用产生了表面等离子体的振荡，可得到宽光谱光的吸收和有效光能的转 换，进而更高效的增强有源介质吸收，大大的改善了太阳能电池转换的效率。 本文是用单晶硅作为太阳能电池的基底结构，球型 Ag 纳米粒子放置在太阳能电池 的背面，利用有限时域差分法对比各项因素对太阳能吸收效率的研究，例如直径分别 为 80nm、100nm、120nm 时，硅基底长和宽为 2μm，厚度为 800nm 时，当直径为 120nm， 周期为 100nm 是最大增益因子 g=1.22；及正面放置直径为 120nm 的时候，光吸收增益 G 与背面放置 Ag 纳米粒子的对比，可以看出在达到最大增益的周期较比背面时较慢。 随后，分别加入 Si3N4 和 SiO2 钝化层对比光增益的比较，通过模拟可以得出 Si3N4 比 SiO2 的折射率高，所以折射率高的钝化层达到的光增益也要高，光当 Si3N4 厚度为 8nm 时达到最大增益 1.173 较比 SiO2 要高；又分别模拟不同钝化层和不加入钝化层的情况 下对比散射截面，可以得出加入钝化层的散射截面发生了红移，加入钝化层由散射产 生等离子体激元效应，长波长处散射多从而达到增大光的吸收，因为 Si3N4 比 SiO2 的 折射率要高，发生红移也要明显。 关键词：单晶硅薄膜太阳能电池；表面等离子体；球型 Ag 纳米粒子；Si3N4、SiO2 钝化 层 ABSTRACT Metal nanoparticle is much more widely used in the solar cells nowadays. Metal nanoparticle enhances the plasmas local resonance effect by using this new cell structure. Because making use of the effect of metal nanoparticle generates the oscillation of the surface plasma, gets the absorption of wide spectrum and the conversion of effective light energy, thus enhances the absorption of the active medium efficiently, as well as greatly improves the conversion efficiency of the solar cell. This paper is the research of the absorption efficiency with the finite-different time-domain method to contrast various data using the monocrystalline silicon as the basement structure of the solar cell and spheroidal Ag nanoparticle placed in the back of the solar cell. For example, when the diameters are 80nm, 100nm, 120nm, the silicon bases length and width are 2μm, the thickness is 800nm, thus when the diameter is 120nm, the period is 100nm as the maximum gain factor g=1.22; And when placing the ones with diameter of 120nm, contrasting the optical absorption gain G and spheroidal Ag nanoparticle placed in the back, obtaining that the period of reaching the maximum gain is later than placed in the back. Then respectively add the comparison of contrasting the passivation layer of Si3N4 and SiO2, resulting in the r