（毕业学术论文设计）-食品级高分子量聚丙烯酸钠的制备.docVIP

PAGE PAGE 食品级高分子量聚丙烯酸钠的制备 摘要 高分子量聚丙烯酸钠(PNaAA)是一类广泛用于烧碱和纯碱行业盐水精制、氧化铝生产的赤泥沉降分离、味精厂废水中蛋白质回收和制糖等行业的高分子材料,也是丙烯酸使用量很大的一类产品。 本文主要介绍了食品级高分子量的水溶性聚丙烯酸钠的合成工艺，包括聚合方法的选择，聚合工艺特点的介绍，反应器型式的选择及过程中搅拌功率的计算等。为了得到聚合工艺过程稳定，得到颗粒形态良好且分子量较高的PNaAA。详细分析了影响高分子量聚丙烯酸钠分子量和粘度的中和温度、单体浓度、单体溶液的pH 值、聚合温度、聚合时间等工艺条件, 得出了最佳工艺条件, 为其工业化生产提供了理论依据。 本实验用水溶液聚合方法合成高分子量的聚丙烯酸钠, 同时试验了用粘度法测定其分子量。经过一系列实验得知在温度50℃左右，PH为11-13，引发剂浓度0.001%左右，聚合时间4-5小时，单体浓度为20%时得到的产品分子量最大为300万。 关键词: 食品级 聚丙烯酸钠　高分子量　制备  Food-grade high molecular weight poly acrylic acid sodium preparation The abstract High molecular weight poly acrylic acid sodium is a widely used in caustic soda and soda industry brine refining, alumina production of red mud Gourmet Powder Factory wastewater separation, in settlement of protein recycling and sugar sectors such as polymer materials. Also is a kind of product of acrylic heavily be used. This article mainly introduced the food-grade high molecular weight water-soluble poly acrylic acid sodium synthesis process, including polymerization method choice, polymerization process characteristics of the introduction, reactor process of type selection and calculation of mixing power etc. In order to get the polymerization process stability, get grain shape good and molecular weight higher PNaAA. Detailed analysis of the effect on high molecular weight poly acrylic acid sodium molecular weight and viscosity and temperature, monomer concentration, monomer solution polymerization temperature, pH value, polymerization time etc, it is concluded that the best technological conditions for its technological condition, provides the theory basis for industrial production. This experiment with solution polymerization methods synthetic high molecular weight polyacrylic acid sodium, and test the determination of its molecular weight with viscosity. After a series of experiments that around 50 ℃ temperature, PH of 11-13, initiator, concentration of polymerization time around 0.001% of 4-5 hours, monomer concentration is 20%