掺铋石英基光纤的制备及其光谱性能研究-光学工程专业论文.docxVIP

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Now the bismuth doped materials have drawn muth attention for its huge proficiency. Dvoyrin reported the first bismuth doped fibers in 2005 and relized laser in the region of 1150-1500nm. Howerer, there are also two factors restrict its further application: (1) the mechanism of the NIR emission is unclear yet and the NIR emission intensity of bismuth is too weak for practical application. (2) It is very hard to prepare the bismuth doped fiber, because the Bi is very easy to volatilize when bismuth doped fiber was prepared in high temperature. Therefore, there is no report that single bismuth doped fiber can emit fluorescence in all optical fiber communication wavelenth. This paper is to solve the above problem. The main topics of this thesis are the methods to enhance the NIR emission and the nature of NIR luminescence. Bismuth doped fiber were prepared to study the spectral properties. The main content of the thesis includes: Aluminum and bismuth co-doped silicate glasses were prepared with reducing agent (Al powder). Effects of Al on the absorption spectrum, NIR emission and visible region emission of bismuth doped glasses was discussed, and compared to the influence of alkali metal on NIR emission of bismuth doped glasses. It is indicated that Bi-related NIR emission center may be attributed to the electronic transition of Bi+. It is discuss the effect of the type of quartz glass tube, dopant ions and preparation process on formation of Bi-NIR active center when perform was prepared. The Bi ions can dope easily when perform was prepared using the lower shrinkage rod temperature tube. Oxidizing atmosphere should be avoided in the preparation of bismuth doped optical fiber, like Yb3+ ion, it is appropriate to increase the reducing atmosphere. Solution doping mathed is batter than gas phase doping mathed when the bismuth doped perform was prepared. It is found the luminescence of perform slice in the wavelength of