超声电沉积锡铋合金研究-物理化学专业论文.docxVIP

２ ２ 改善和优化了操作条件；另外，由于超声波的作用，添加剂的用量明 显加大。 对电沉积锡铋合金的作用机理进行了初步探讨，通过对电沉积锡 铋合金的极化曲线和循环伏安曲线的测量表明，添加剂的加入和超声 波的介入都使阴极的极化增加，改变了电极过程，使结晶生长机理得 到改良。对不同条件下电沉积样品的 XRD 进行的测试也表明，超声波 作用的沉积层具有择优织构，并且晶粒更细致，结合力更好，从而使 耐蚀性和可焊性更优良。采用这种工艺操作简单易行，对传统的工艺 改造也较容易，因此，具有很大的实际应用价值和应用前景。 关键词：超声波；电沉积；锡铋合金；添加剂；沉积机理 Study On The Electrodeposition of Tin-Bismuth Alloy Using Ultrasound ABSTRACT Electrodeposition or electroplating is adopted to deposit metal layer in the metal surface for the sake of surface function that changes solid material or making the metal material take particular composition with function. Because the electrodeposits have good adhesion, the crystallize is small but again uniform, and can acquire the good physical and chemical functions. It is usually used for protection, decoration and satisfying the other special requests. And electrodeposits are very widely applied in machine, electronics, automobile, national defense, and aviation industry etc. Products with pure Tin deposits are widely used in electronics industry and light industry. For many years, many domestic and international electrochemistry scholars have studied on the acidity Tin electrodeposition. Because the shining Tin deposits obtained from acidic aqua have many advantages such as quick depositing speed, good solderability, better corrosion-resistance and etc. Up to now, the method is still extensively applied in production. The shining Tin-Bismuth alloy that obtained from acid electrolyte has many advantages. Such as compact structure, few holes, better resistance to oxidation and etc. Especially the solderability is very ideal. Thus, it is prospected to substitute solderable Tin. But to get satisfactory layers, the function of the additive is one of the key factors. In this paper, a kind of multi-functional additive was prepared, which can get at the same time the functions of shine, disperse and stabilization. The results show that the deposits are good: The crystallite is s