掺Ce稀土硅酸盐介孔发光材料的制备及性能研究-分析化学专业论文.docxVIP

中文 中文摘要 3 3 摘 要 稀土元素独特的 4f 电子构型，从而具有多种优越的光学性能，有着极其广 泛的应用。介孔材料因其比表面积大、孔隙率高、孔径分布窄等结构特点而具备 许多独特的物理和化学性质，而且其孔道表面还可通过物理吸附或化学修饰引入 一些功能分子而形成新的功能材料，从而使其在催化、吸附、分离、光、电、磁 等诸多领域有着广阔的应用前景。纳米材料也因具有小尺寸和表面效应等特点得 到迅速发展。本文将稀土元素 Ce 掺杂进入了硅酸盐中，将其制备成了介孔材料 和纳米材料，进而对它们不同的光学性质进行研究。本文主要的工作及结论如下： 1. 用液晶模板法，以非离子三嵌段高聚物P123为模板，通过调节反应介质 的酸度，优化稀土掺杂介孔分子筛合成的酸性条件；并且对煅烧前后的介孔材料， 没掺杂敏化剂的发光材料的荧光性能进行了对比。也改变Y与Ce的掺杂比例考查 了其介孔状态和发光性能的变化。通过FT-IR、XRD、BET、HRTEM和荧光光谱 等对产物进行了表征。分析结果显示：0.4为反应体系的最佳PH值，这个PH值条 件下样品荧光强度最强；经过500℃煅烧后，有机模板剂去除比较完全；当nY/nCe=4 时，材料的BET比表面615m2/g，平均孔径为4.34nm，孔径分均匀而有序，发光 强度最强。 2.用溶胶-凝胶法制备了纳米粉体发光材料Y1.6SiO5∶Ce0.43+,并通过FT-IR、 XRD、TEM、荧光光谱等方式对其进行了表征。在不同温度下对样品进行煅烧 处理。结果显示，煅烧温度的升高对纳米材料的晶体结构和发光性能有着显著的 提高。将介孔发光材料和纳米颗粒发光材料进行比较，纳米材料结构上更显精细， 纳米材料有着较好的晶形，而介孔材料则是非晶态。纳米材料的发光性能也较好。 关键词：Ce，荧光，介孔材料，纳米颗粒， 英文 英文摘要 II II Abstract The nanopaticles and mesoporous materials have showed many unique physical and chemical properties because of their structural features such as large specific surface area, high porosity and narrow pore size distribution. The rare-earth ions doped nanopaticles and mesoporous materials have gotten extensive application in the fields of catalysis, adsorption, separation, light, electricity, magnetism. The rare-earth element Ce doped nanopaticles and mesoporous materials in the thesis were prepared by doping rare-earth element Ce into silicate, and their optical properties were investigated. The main contents are as follows. Mesoporous rare earth luminescence material with Ce was perapared by liquid-crystal template method using non-ionic P123 as the template, the preparation conditions of the rare-earth Ce doped Y2SiO5 mesoporous materials were optimized by adjusting the acidity of reaction medium. Their structure and properties were characterized and evaluated by FT-IR, SAXRD, HRTEM, nitrogen adsorption-desorption isotherm, and fluorescence spectra. The results show that the mesoporous materials obtained at pH value 0.4 of reaction solution and calcined temperature of 500oC show the stron