层状三钛酸盐光催化剂的掺杂与插层改性研究-材料学专业论文.docxVIP

万方数据 万方数据 华侨大学硕士毕业论文 Abstract With the development of human society, energy crisis and environmental pollution have become a series of problems. The semiconductor-based photocatalysis has attracted widespread attention, which provides an effective approach to solve such problems, and the preparation of visible-light-active photocatalysts is of great importance. Layered titanates have good photocatalytic activity, functional cationic or appropriate semiconductor can be inserted into their interlayer to fabricate a heterojunction, which not only expand the light response of materials to the visible light but also increase the separation rate of the photogenerated carriers. In this dissertation, H2Ti3O7, a titanate layered compounds with a high photocatalytic activity, has been used to prepare modified nanocmoposites. The photocatalytic nanocmoposites have been successfully prepared using Ti3O72- nanosheets with Cu2+, Fe2O3 and CdS as building blocks via an exfoliation-restacking route. The as-prepared cmoposites were investigated by means of XRD, SEM, TEM, UV-Vis DRS, XPS, N2 adsorption-desorption isotherms and other technologies. The photocatalytic activities of these cmoposites were also evaluated. Firstly, novel mesoporous Cu-Ti3O7 nanohybrid was assembled by the negative exfoliated Ti3O72- nanosheets and simple Cu2+ cations. It was revealed that the present nanohybrids are mesoporous with specific surface areas of about 182 m2/g. The intercalated nanohybrids exhibit good photocatalytic activities in the degradation of methylene blue under visible-light irradiation (λ ≥ 420 nm, from a filtered 300 W Xe lamp). The superior photocatalytic performance is predominantly attributed to Cu2+, which effectively adjust the band structure of the semiconductor, reduced the width of band gap, expanding the scope light response of the material. Secondly, Fe2O3 sol was used as the positively electronical guest nanoparticles to prepare Fe2O3-H2Ti3O7. It was observed that the F