多元金属硫化物电极材料的制备及其超级电容器性能的研究-无机化学专业论文.docxVIP

摘要 制备具有卓越形貌和理想组分的高性能超级电容器电极材料提供了很有价值的 参考。 三、与单金属硫化物相比，多元金属硫化物作为超级电容器的电极材料时， 具有较高的比容量和倍率性能，但是，其电化学性能仍不能满足众多研究者的需 求。然而，石墨烯具有比表面积大、导电性强和机械性能好等优点被广泛的用于 材料的复合，进而提高电极材料的电子传输性能。基于以上，我们采用简单的水 热 反 应 成 功 的 将 质 量 分 数 为 5% 的 还 原 石 墨 烯 （ rGO ） 引 入 到 CoS1.097 、 Ni0.22Co0.78S1.097、Ni0.46Co0.54S1.097 和 Ni0.48Co0.52S1.097 微纳米材料中制得相应的复 合材料，并将其用于超级电容器的电极材料，通过循环伏安和恒流充放电测试， 发现 NixCo1-xS1.097-rGO（x=0,0.22,0.46,0.48）复合材料的电化学性能明显高于 相应硫化物的电化学性能。 关键词：金属硫化物 协同作用 超级电容器 高倍率性能 II Abstract Along with the rapid development of science and technology, more and more researchers have been showing great interest in high performance electrochemical energy storage devices. Supercapacitor, as a king of electrochemical energy storage devices, has drawn particular attention because of its high energy density, long cycle life and fast charging and discharging. The electrochemical properties of the materials of supercapacitors are determined by materials composition, crystalline morphological and specific area. Thus, controllable syntheses of electrodes with desirable composition and special architecture are expected to have remarkable potential for generating high-performance supercapacitors. In this work, we have successful synthesized a series of new and hierarchical structured multiple sulfide electroactive materials using cobalt coordinated compounds under moderate condition. And these synthesized materials were used as electrode materials for supercapacitor, exhibited excellent and tunable electrochemical performance. The details are summarized briefly as follows: Firstly, single crystal of cobalt coordination compounds were obtained via the reaction of cobalt (II) sulfate with trimesic acid (H3TMA = 1, 3, 5-benzenetricarboxylic acid) by one-pot hydrothermal reaction. Nickel ion exchange was used to produce the Ni–Co hetero-metal compound with tunable chemical composition. Single-crystal to single-crystal transformation has been achieved. Using a nickel-exchanged compound as the precursor, we developed