负载纳米氧化铁活性炭去除水中重金属铜实验的研究.docVIP

负载纳米氧化铁活性炭去除水中重金属铜实验的研究 　　文章编号： 1008-8857(2014)02-0068-05DOI:10.13259/j.cnki.eri.2014.02.002 　　 　　摘要： 采用两种制备方法(M1、M2),分别对三种活性炭(AC1、AC2、AC3)进行负载纳米氧化铁实验研究.通过不同材料对Cu(Ⅱ)吸附量的筛选实验,得出 AC2M2对Cu(Ⅱ)吸附量最大.对AC2M2进行的静态吸附实验研究结果表明:pH值在1~6范围内,AC2M2对Cu(Ⅱ)的吸附量随pH值增大而增加;AC2M2对Cu(Ⅱ)的吸附规律符合Langmuir吸附等温模型和准二级动力学模型,与AC2相比,其最大吸附量提升了约113%,其吸附过程分为快速吸附、慢速吸附、动态平衡三个阶段;AC2M2对Cu(Ⅱ)的吸附是自发吸热过程,吸附机理主要以物理吸附为主,并同时存在化学吸附. 　　关键词： 活性炭; 纳米氧化铁; 重金属; 铜 　　中图分类号： X 52文献标志码： A 　　Experimental study on removal of Cu(II) by nanosized 　　iron oxide loaded activated carbon 　　LU Xiao??kai, XU Zhi??hua, LI Ya??ru, YUAN Shi??jue 　　(School of Environment and Architecture, University of Shanghai 　　for Science and Technology, Shanghai 200093, China) 　　Abstract： Nanosized iron oxide was loaded onto three kinds of activated carbon (AC1, AC2, AC3) by two preparation methods (M1, M2). Within these materials, the results of screening tests of adsorption showed that AC2M2 has the maximum adsorption capacity of Cu(II). Batch adsorption experiment was carried out on Cu(II) adsorption by AC2M2. It was found that Cu(II) adsorption capacity of AC2M2 increased with solution pH from 1 to 6. The adsorption behavior of Cu(II) on AC2M2 obeyed Langmuir isotherm model and pseudo??second??order kinetic model. Compared with AC2, the maximum Cu(II) capacity of AC2M2 increased approximately 113%. The adsorption process was divided into fast adsorption stage, slow adsorption stage and dynamic balance stage. Adsorption thermodynamic data indicated that Cu(II) adsorption onto AC2M2 was a spontaneous endothermic process, and the adsorption mechanism mainly depended on physical adsorption and chemical adsorption existed at the same time. 　　Key words： activated carbon; nanosized iron oxide; heavy metal; copper 　　随着我国工业化不断发展,涉及重金属排放的行业越来越多,水体重金属污染日趋严重.含铜废水是一种较常见的重金属废水,广泛存在于电镀、金属冶炼等行业中.过量的铜离子长期存在于水体中,不但对水生生态系统造成破坏,而且能通过食物链进入到人体内危害人类的健康.在众多重金属处理方法中［1］,吸附法因其具有高去除率、低成本、易操作等优点成为一种优先选择的去除水体重金属的处理方法.活性炭是水处理领域中最常使用的吸附剂,但由于其自身的吸附特性,对有机物的去除效果较好,而