芳砜酰胺共聚物溶液的干喷湿纺研究-材料加工工程专业论文.docxVIP

东华大学 东华大学硕士论文 芳砜酰胺共聚物溶液的干喷湿纺研究 万方数据 万方数据 干喷湿纺的初生纤维中已经开始形成取向结构，并且在凝固拉伸过程 中形成良好的取向结构。随干喷湿纺过程，纤维形成更好的取向纤维 结构并逐渐增强，热拉伸后，增强了分子间次价键作用，在纤维强度 增加的同时，断裂伸长率基本不变。 最后，通过小角 X 射线散射，扫描电镜结合拉伸测试，分析研 究成形工艺条件（纺丝线上张力、凝固浴条件、喷丝头牵伸比、空气 段长度）变化时，纤维沿纺程成形的结构变化。结果发现，纺丝线上 张力的提高使纤维形成更加紧密和沿轴向的取向结构，但是过高的张 力反而会破坏正在成形的纤维中的取向结构。初生纤维中有序结构受 到凝固浴温度、喷丝头牵伸比和空气段长度的影响，纤维的可拉伸性 受到喷丝头牵伸比，空气段长度和凝固浴浓度的影响。co-PSA 干喷 湿纺的第一凝固浴牵伸过程中，牵伸对象为处在空气段的纺丝溶液， 并且初生纤维的有序结构在进入凝固浴之前形成。干喷湿纺中决定纤 维是否出现皮芯结构的因素是凝固浴的浓度。 关键词：芳砜酰胺共聚物溶液，流变特性，干喷湿纺，形态结构与性 能 iv STUDY ON THE DRY-JET WET SPINNING OF AROMATIC COPOLYSULFONAIMDE ABSTRACT Polysulfonamide (PSA) is well-known as excellent thermal stability, electrical insulating, acid and alkali resistance, and flammability, with many applications in high-temperature filtration and firefighting. The investigation was focus on dry-jet wet spinning of polysulfonamide copolymer (co-PSA) solution，which includesthe study of spinning solution stability, the research of changes of performance and morphology during the spinning process, and the explore of spinning process influence on fibers forming. From the study of the rheological behavior of co-PSA spinning solution, a typical behavior of concentrated polymer solution was observed.From the dependence of zero-shear viscosity on temperature, it is shown that the flow activation energy (Eη) of co-PSA spinning dopes varied little with different intrinsic viscosity, about 23KJ/mol, which indicated that the spinning dope of co-PSA is stable to temperature.From the dynamic rheological behavior of PSA spinning dope, the scale between the dynamic modulus (the storage modulus G’ and loss modulus G”) and angular frequent (ω) were 1.0 and 2.0 respectively at the low frequency while 0.2 and 0.5 at the high frequency accordingly, which proved the spinning dope had the characteristic of homogeneous solution in the range of experimental temperature. No gelation transition was observed from the further temperature sweep analysis, which also indicated that the spinning