芳香性多齿甜菜碱类衍生物的氢键包合物和金属配合物的制备及结构分析-化学专业论文.docxVIP

万方数据 万方数据 coordination, and both carboxylate groups of L2 molecule moledendately ligate to Zn(II) atom, thus forming a bucket-like discrete coordination molecule. By π–π interactions between the aromatic rings, the molecules of 5 are arranged to a layer pattern. (4) In 11, the central Mn(II) atom is coordinated by two carboxylate groups each from a molecule of L5 forming a discrete coordination cation, Hydrogen bonds between the lattice water molecules, aqua ligands and coordination free carboxylate groups link the cartions to a layer containing tunnels. On the other hand, coordination free L5 molecules are linked by hydrogen bonds between water molecules and carboxylate groups to zig-zag chains, which penetrate different lays thus resulting a three-dimensional structure. (5) Compounds 7, 8 and 9 are inclusion compounds with L3 and water molecules forming host framework, and organic small molecules DMSO, 4,4’-bypyridyl and benzene-1,3-diamine as guest entities. In both 7 and 8, adopting “U” conformation and oppositely aligned L3 molecules are linked by hydrogen bonds between carboxylate groups and water molecules producing tubes. The neighboring tubes are agglutinated by π–π stacking thus generating the host framewoke, and DMSO or 4,4’-bipyridyl molecules are hosted inside the tubes. There are no significant interaction between the guest molecules and the host framework other than van de Waals interactions. However, in 9 one of the -NH2 groups on benzene-1,3-diamine molecule forms strong hydrogen bond with the carboxylate group of L3 molecule , which destroys the tube structure, and another kind of inclusion compound is resulted. KEY WORDS：Coordination compound, includion compound, Crystal Structure, Hydrogen Bond Network, π–π Stacking, 目录 目录 目 录 HYPERLINK \l _bookmark0 第一章 前言 1 HYPERLINK \l _bookmark1 1.1 羧基的性质及配位模式 1 HYPERLINK \l _bookmark2 1.1.1 羧基的性质 1 HYPERLINK \l _bookmark3 1.1.2 羧基与金属离子常见的配位模式 3 HYPERLINK \l _bookmark4 1.2 配位化合物形成拓扑结构的影响因素 7 HYPERLINK