纯有机DSSC材料与器件研究-信息材料专业论文.docxVIP

万方数据 万方数据 关键词: DSSC，D-π-A染料，静电喷雾，咔唑 II Abstract Dye is an important component of dye sensitized cells (DSSC), because it plays a key role on the photoelectric conversion efficiency of DSSC. In recent years, with the fast development of DSSC, the dye is becoming one of the hot topics of DSSC research. Currently, dyes of heavy metal complexes are the mainstream photo sensitizers in DSSC devices due to their high device efficiency. However, metals inside the dyes are rare elements in nature, thus material supply is extremely insufficient for mass production. Metal-free organic dyes have many merits, such as abundant in nature, tunable in molecular structure, easy purification and low environmental pollution, which is promising to DSSC application. At present, the performance of DSSCs based on metal-free organic dyes cant meet the requirement for commercialization, demanding further development both in aspects of efficiency and stability. This thesis focuses on the investigation of metal-free organic photosensitizer of DSSC, and further explores the relationship of device performance and material structure. There are mainly three parts in our work: Design, synthesis and characterization of dyes. In this part, the four target products, i.e. (Z)-3-(5-(4-((9H-carbazol-9-yl)methyl)phenyl)thiophen-2-yl)-2-cyanoacrylicacid (CBR), (Z)-3-(5-(4-(9H-carbazol-9-yl)phenyl) thiophen-2-yl)-2-cyano acrylic acid (CI), (Z)-3-(8,9-bis(decyloxy)-5-(9-(2-(2-methoxyethoxy)ethyl)-9H-carbazol-3-yl)naphtho[1,2-b:4,3-b]d ithiophen-2-yl)-2-cyanoacrylic acid (CNDT1) and (E)-2-cyano-3-(5-(9-decyl-9H-carbazol-3-yl)-8,9-bis(decyloxy)naphtho[1,2-b:4,3-b]dithiophen-2-y l)acrylic acid（CNDT2）, were prepared by chemical bonding of different potential functional groups and using various types of reactions. Then the structure of dyes, including intermediate of them, were characterized by 1H-NMR, 13C- NMR, IR and HRMS. Investigation on DSSC devices based on CBR and CI. CBR and CI are two new D-π-A type meta