协同催化型复合钴盐FH201在子午线轮胎带束层胶料中的应用.docVIP

“协同催化型”复合钴盐FH-20-1在 子午线轮胎带束层胶料中的应用 岳鹏远搔春屢吴明生曹长青 青岛科技大学化工学院青岛科技大学橡塑材料与工 程教育部重点实验室 使用全钢子午线轮胎带束层胶料配方，研宄了 “协同催化型”复合钴盐 FH-20-1的用量对胶料的硫化特性、硫化胶的物理机械性能、与带束层钢丝粘合 性能的影响，并探索了其促进粘合的机理。结果表明：随着FH-20-1用量的增加, 胶料的最高最低转矩差值增大，焦烧时间和工艺正硫化时间减少，表明 FH-20-1有提高交联密度、促进硫化的作用；随着FH-20-1用量的增加，硫化胶 的拉仲强度、100%定仲应力、拉断仲长率以及撕裂强度都呈现先增大后减小的趋 势，在0. 6份时效果最佳;与加入0. 9份的新癸酸钴或0. 9份的硼酰化钴胶料相 比，当FH-20-1用量为0.6份吋，胶料与钢丝的粘合力优于前者，与后者相差不 大，而力学性能和耐老化性更突出；经过热失重分析，FU-20-1的初始分解温度 比新癸酸钴的低，表现出更高的化学活性。FH-20-1的钴含量约为新癸酸钴的 75%,且其用量为新癸酸钴的70%，胶料中钴含量仅为新癸酸钻胶料的50%左右， 初步实现了钴盐粘合剂“低钴化”的目标，并能降低用户的产品成木。 关键词： 协同催化;复合钴盐;粘合;带束鼠生产成本; 岳鹏远（1991 一），男，硕士研宄生. 2016-11-01 Application of Composite Cobalt Salt FH-20-1 as J Concerted Catalysis’ in Belt Compound of Radial Tire YUE Pengyuan YANG Chunying WU Mingsheng CAO Changqing College of Chemical Engineering， Qingdao University of Science and Technology; Key Laboratory of Rubber-Plastics， Ministry of Education， Qingdao University of Science and Technology; Abstract： In this paper, the rubber formulation of belt in radial tire was used.Through researching on the amount of the composite cobalt salt FH-20-1 which is served as1 concerted catalysis，the influence on the vulcanization characteristics, physical and mechanical properties of vulcanized rubber and adhesive property of compound with belt layerz s steel are obtained, the mechanism of promoting adhesion is also discussed. The results shows that withamount of FH-20-1 increasing, the torquez s difference between the maximum and minimum increase, the scorch time and the process curing time is shorten. This shows that FH-20-1 has the function of improving crosslink density and promoting vulcanization. With the amount of PH-20-1 increasing, the tensile strength, tensile stress at 100%， elongation at break and the tearing strength increase first and then decrease, and 0. 6 phr has the best effect. Compared with compound which is added 0. 9 phr cobalt neocaprate and 0. 9 phr cobalt boronacylate, when the amount of F1F20-1 is 0. 6 phr, the adhesive pro