低温固体氧化物燃料电池结构改进-材料学专业论文.docx

Abstract Abstract IV IV ion-impregnated SDC nanoparticles can accelerate the oxygen surface exchange process thus decrease the interfacial polarization resistance. In chapter four, we focus on the configuration of electrolyte. Doped ceria (DCO) as alternative electrolyte in low and intermediate temperature SOFC usually causes drop in open circuit voltage (OCV) as reduction of ceria in anode atmosphere. To cut the current leakage caused by reduction of DCO, an electronic block layer was added to form the bilayer electrolytes. In the first section, scandium stabilized zirconia (ScSZ) was used as electronic block layer and the cell configuration is NiO-SDC//ScSZ/SDC//SSC-SDC. After adding ScSZ layer, OCV increased to above 1.0V, peak power density reached 625mWcm-2 and maintained stable within 60 hours at 600 oC. In the second section, Y0.25Bi0.75O1.（5 YSB）was used as the electronic block layer. Though the improvement in OCV is not obvious, the high conductivity of YSB reduced the ohmic resistance. When choosing LSM-YSB ceramic as cathode, the peak power density reached 266 mWcm-2 at 600 oC and maintained stable within 100 hours. To further decrease the resistance in cathode, Ag-YSB was used as cathode. Cell configuration of NiO-SDC//SDC/YSB//Ag-YSB can reach a peak power density of 223 mWcm-2 at 500 oC. However, the Ag particle in cathode is easy to agglomerate, and its long time stability is not satisfying. This may be solved by impregnation Ag into the YSB matrices. In Chapter five, we try to reduce the operating temperature below 500 oC by decreasing the electrolyte thickness via spin-coating technique, optimizing microstructure both in electrolyte and anode adopting a two-step sintering process. The spin-coating technique can effectively control the coating thickness by varying the coating cycles. The precipitated SDC powders used in suspension with pre-heated at 1300 oC shows high co-sintering ability with the anode substrate and thus resulting in high e