富勒烯的化学修饰与表征-分析化学专业论文.docx

II II Chemical modification and characterization of fulleneres Abstract Solar energy is one kind of clean and renewable energy which is rare and available. Using solar cells is one of the main ways to get solar energy. Because of some merits, such as ease of large scale manufacturing, low cost, light weight and compatibility with flexible substrates, the development of organic polymer photovoltaic cells becomes more and more important. But Fullerene C60 has some disadvantages, such as phase separation and cluster effect in process of preparation, chemical modification of Fullerene C60 is necessary. This paper designs and synthesizes some fullerene C60 derivatives. Firstly, utilizing the Meldrum’s acid as starting materials, the malonic acid mono ester was synthesized by esterification with dodecanol, then reacted with t-butanol, a symmetric malonic acid di-ester was prepared, finally one fullerene C60 derivative (2-1) was synthesized by Bingel reaction, and its photovoltaic properties were characterized by cyclic-voltammetry (CV) and UV spectram. Meanwhile, the deprotective reaction of compound (2-1) was investigated. Then we designed a new fullerene derivatives based on the growth of carbon chain which can increase the solubility. Hydroquinone and bromine octane as starting materials were used to prepare alkoxy phenol through Williamson reaction, the optimum reaction conditions was obtained by orthogonal test. The alkoxy phenol was reacted with Malonic acid to prepare asymmetry ester with malonic acid functional groups, then reacted with hydroxyl compounds. An asymmetric double ester containing malonic acid functional groups was prepared, finally one fullerene C60 derivative (3-1) was synthesized by Bingel reaction, This fullerene derivative (3-1) has long carbon chain and its photovoltaic properties were characterized by cyclic-voltammetry (CV) and UV spectram. In order to improve the solubility of fullerene derivatives which took off the tertiary butyl, the subst