等离子喷焊钴基WC复合耐磨涂层组织与性能探究-材料工程专业论文.docx

哈尔滨工业大学工程硕士学位论文 哈尔滨工业大学工程硕士学位论文 万方数据 万方数据 Abstract With consideration of the damages of mechanical equipment in die industry and metallurgy, improving the wear and corrosion properties of the workpiece is an important way to increase their service life. The PTAW deposited resistant overlays is the key direction at present. In present paper, orthogonal experiment is used to explore the influence of process parameters on deposited overlays. The influence of the tungsten carbide particle addition on the microstructure, microhardness and wear behavior of PTAW coatings deposited on Q235 steel substrate has been reported, and the strengthening mechanism is analyzed. The study found that the larger the Mass Energy (The average energy for unit mass of powder and shadowed substrate) is, the dilution rate of coatings is higher.a good forming of coating can be achieved with the Mass Energy of 110 ~ 133J/g. With the νg (spray velocity) at 80~120mm/min, the increasing of Mass Energy induces three evolutions of coatings: Firstly, the Co6W6C, Fe6W6C in W-rich phase gradually disappears. Secondly, with the degree of WC melting increases, M23C6 precipitates a major precipitation of hardening phase. Thirdly, with the degree of iron melting increases, Laves phase of Fe2Si precipitates with oriented grown. The main factors of wear resistance, hardness, dilution rate of the coatings are studied by the orthogonal experiment. Optimal parameters for wear resistanced coating is gived below: spray current : 60A, powder flow :23.5g/min, νg :80mm/min. When WC content is lower than 20%wt.%, the solid solution will be formed first, followed by the precipitation of the eutectic crystallization with the shape of small dendritic inside the solution. With the increase of WC content, the WC as nucleation sites , the proportion of heterogeneous nucleation crystallization with WC increases, the eutectic precipitation outside the solution increases ; The matrix gradually precipitates with the shape of f