稻壳多孔炭吸附材料的制备及其在废水处理中的应用-环境科学专业论文.docx

Preparation of Porous Carbon Adsorption Materials from Rice Husk and Application in the Wastewater Treatment Postgraduate: Liao Qinhong Supervisor: Professor Meng Mianwu Major: Environmental Science Field: Environmental Material Grade: 2007 Abstract Rice husk-based porous carbon were prepared by using H3PO4 and K2CO3 according to the development and shortcoming of porous carbon adsorption materials. The effects of the technologic factors of activation temperature, activation time, activation agent concentration, impregnation ratio and time on the yield and iodine adsorption performance of activated carbon (AC) were systematically investigated after using thermogravimetry to analyse the pyrolysis mechanism of rice husk, carbonized rice husk removed silicon, rice husk/ H3PO4, carbonized rice husk removed silicon/ H3PO4, rice husk/ K2CO3, carbonized rice husk removed silicon/ K2CO3. The main technology factors which affected the yield and absorption performance of rice husk-based activated carbon were sifted by Plackett-Burman (P-B) design, prediction model of iodine adsorption number were developed by using central composite design (CCD). The BET surface area, pore size distribution, microstructure, phase structure, surface functional groups were investigated by using specific surface area analyzer(BET), scanning electron microscope (SEM), X-ray diffraction (XRD), fourier transform infrared spectrometer (FT-IR), respectively. The adsorption effect of methylene blue dye was also investigated by activated carbon using K2CO3 activation method. The results were showed as the following: The activation energy and preexponential factor of rice husk and carbonized rice husk removed silicon in the pyrolysis temperature range (490～640K, 490～1020K) were 47.3 KJ/mol, 1.73×103 min-1 and 8.04KJ/mol, 5×10-2 min-1, respectively. The carbonization temperature was reduced 70K by the activation agent H3PO4, and the pyrolysis temperature range