TiO2壳聚糖复合膜降解甲基橙的研究-三明学院.PDFVIP

2014年 12月 三 明 学 院 学 报 Dec.2014 第31卷 第 期 JOURNAL OF SANMING UNIVERSITY Vol.31 No. 凿燥蚤院员园援员源园怨愿辕躁援糟灶猿缘原员圆愿愿辕 扎援圆园员源援园 援园15 TiO/壳聚糖复合膜降解甲基橙的研究 2 张秀华袁陈梅金袁周云龙袁胡志彪袁陈宝銮 渊龙岩学院 化学与材料学院袁福建 龙岩袁364012冤 摘要院采用流延成膜法袁以戊二醛为交联剂制备TiO/壳聚糖复合膜遥 用X射线衍射仪袁傅立叶红外光谱仪以及2 扫描电镜对复合膜进行表征袁并研究了不同戊二醛含量对壳聚糖膜溶胀率的影响遥 以甲基橙降解反应为模型袁研究 TiO辕 壳聚糖复合膜降解染料废水的性能遥 结果表明院TiO 与壳聚糖相容性较好袁 加入TiO 可提高复合膜的机械强2 2 2 度袁 戊二醛交联能有效抑制膜的过度溶胀曰 复合膜对甲基橙的降解效果良好院 当复合膜用量为0.30g袁 初始浓度为 5mg/L 甲基橙溶液50mL袁pH 为2.36袁紫外光照射80min袁降解率可达到85%以上袁具有较好的应用前景遥 关键词院壳聚糖曰二氧化钛曰戊二醛曰复合膜曰降解 中图分类号院O636 文献标志码院A 文章编号院1673-4343渊2014冤06-0076-05 Study on the Degradation of Methyl Orange by TiO/Chitosan Composite Membrane2 ZHANG Xiu-hua, CHEN Mei-jin, ZHOU Yun-long袁HU Zhi-biao, CHEN Bao-luan 渊College of Chemistryand Materials袁Longyan University,Longyan 364012,China冤 Abstract: Byasolutioncastingtechnology,theTiO/chitosancompositemembranewaspreparedthroughusingglu- 2 taraldehyde as a cross-linking agent. The composite membrane was characterized by FTI Rand XRD, and the effect of swellingrateresultingfromvariousquantityofglutaraldehyde was also investigated. Degradation ofmethyl orange in the presenceofTiO/chitosancompositemembranewasstudied.TheresultindicatedthattheconsistencybetweenTiO andchi- 2 2 tosan was good; the mechanical propertywas strengthen bythe adding ofTiO , and the glutaraldehyde could control the