高分子共混体系相分离相场模拟-高分子物理专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 II万方数据 II 万方数据 Abstract The macromolecule alloy has excellent combination property including physical properties, mechanical properties which can satisfy modern people’s pursuit of better quality of life.In the mean time,it relieves the contradiction between the singleness of the performance of traditional single polymer material and the production also living demands. One kind of the macromolecule alloy with the characteristics of phase separation has attracted a great amount of attention because it generates a special micro structure during phase separation ,thereby giving the alloy superior features.Therefore, how to control the forms of micro structure by studying the mechanism of phase separation and the characteristics of different polymer blends is the focus of obtaining polymer alloys which have the excellent performance and use value. This article was based on the phase-field theory, and summarized the thermodynamics and dynamics during the phase separation. By Combining the Ginzburg-Landau free energy with the classical diffusion law, we deduced the binary phase-field model under the influence of the molecular weight and gradient energy coefficient and also the ternary phase-field model. Keeping the molecular weight of one component a constant, we studied how the variation of molecular weight in the other component affect the phase separation. It turned out that the molecular weight plays a dual role in phase separation, and ultimately brought a kind of regular pattern to phase separation. We studied the influence of gradient energy coefficient on the phase separation from the perspective of one-dimensional and two-dimensional, and the result indicated that the introducing of the entropy contribution of coefficient slowed the rate of phase separation in the early and middle stage and reduced the growth index of the late stage. On the basis of the ternary model, we summarized the results and described the phase structure with a ph