高分子吸附剂的制备及其应用-化学工艺专业论文.docxVIP

摘 摘 要 摘 要 研究了用吸附剂去除汽轮机油和空气中微量水分的工艺，采用水溶液聚合法制 备了一种吸水速度快、吸水倍率高的高分子吸附剂。在合成该种高分子吸附剂的过 程中着重研究了吸水倍率和吸水速率的影响因素，并通过一系列改性方法改善产品 的综合性能。 通过正交实验法研究了单体、交联剂和引发剂对吸附剂吸水倍率和吸水速率的 影响，缛到了制备高分子吸附剂的最佳配比和工艺。继而采取添加水溶性高分子、 表面活性剂、进行表面交联反应、添加致孔剂等方法进行改性，经实验分析表明， 加入水溶性高分子、表面活性剂、对产品进行表面交联均对吸附剂的吸水倍率或吸 水速率有一定量的改善，对综合性能的提高效果不明显，致孔剂的添加使吸附剂的 综合性能有了很大的提高，本文选用液体石蜡与三氯甲烷为致孔剂，分别对两种致 孔剂的不同添加量进行了实验，结果表明当液体石蜡与三氯甲烷按照1：2的比例， 添加量为3％(对于单体丙烯酸，、Ⅳl％)时，产品的吸水倍率和吸水速率效果最高。 采取吸附剂于无纺布共混聚合制得复合型吸附剂。应用于对汽轮机油和空气中 微量水的吸附，结果表明吸附剂对于汽轮机油中微量水的吸附效果好，吸附后的汽 轮机油可以达到工业要求；在吸附空气中微量水时，设计吸附流程，并自行设计一 套除去气体中水蒸气的发生吸附装置，这对工业生产中去除微量水分的工艺有一定 的指导意义，也是本文的创新之处。 图7表22参65 关键词：高分子吸附剂；丙烯酸；水溶液聚合；致孔剂 分类号：TQ072 河北理工大学硕士学位论文Abstract 河北理工大学硕士学位论文 Abstract nlc lligh molecular sorbent was prepared by solution polymerization in this article，which Was characterised by high water absorbency and the rate of absorption,aimed at the removal of the trace water in the turbine oii and air．The effect on the water absorbency and the rate of absorption propertyes mainly discussed and modifications were applied to improve the multiple-properties．Besides a lot of additives are adding to meliorate the properties ofthe hi【gh molecular sorbent． The paper treated of the influence of monomer,crosslinking agent and initiator to water absorbency and the rate of absorption through the method of orthogonal experiment and the optimum process conditions obtained．The properties ofthe lxigh molecular sorbent are modified by adding additives(water-soluable polymer、surfactant、porogenic agent、 and crosslinkirtg reaction on its surface)on the base of adding initiator、crosslinking agent to the polymerization system．The results showed that the water absorbency or the rate of absorption is meliorated，but multiple properties wele not improved，yet the porogenic agent was of improving the multiple properties．The paper used the liquid paraffin and chloroform as pomgenic agent，dealed with the influence of different quantity of the porogenic agents，the result showed that the high molecular sorb