《电镀锌钝化工艺研究》-毕业设计论文（学术).docVIP

长 春 工 业 大 学 毕 业 论 文 题 目：电镀锌钝化工艺研究 学 院：材料科学与工程学院 专 业：金属材料工程 班 级： 姓 名： 指导教师： 2012年 6 月 9 日 PAGE \* MERGEFORMAT I 摘要 锌在空气中不易发生变化，因为在空气中，表面生成一种很致密的碱式碳酸锌的薄膜，而这种薄膜能够有效保护内部不受到腐蚀。当某种原因，使镀层发生破坏而露出钢基体时，锌与钢基体形成微电池，使钢基体成为阴极而受到保护。镀锌层较厚，结晶细致、均匀且无孔隙，抗腐蚀性能良好。它在酸、碱等雾气中腐蚀较慢，能有效的保护钢基体，且经过铬酸钝化后形成白色、彩色、军绿色等，美观大方，具有一定的装饰性。本文通过研究电镀锌及以后的钝化的各种工艺方法，并且所得到的钝化膜进行各种性能和测试与评定,找到较合适应用的工艺方法。采用X射线衍射仪、日产JSM—5600型扫描电子显微镜和多功能电子能谱等分析手段，对镀锌层的成分、微观形貌和结构、腐蚀产物、钝化膜的结构和成分进行了分析和研究。采用电化学实验法对镀锌层及各种钝化层地耐蚀性进行了研究。 关键词：电镀锌 钝化 耐腐蚀性 Title: The research of Zn electroplating technology and the passivation film properties ABSTRACT Since zinc is not easy to change in the air, substrate to a very dense surface of basic zinc carbonate film, and this film effectively protects zinc from the internal crrosion.For some reason, the destruction of the coating occurred in the steel substrate and it is not exposed, the zinc and steel substrate to the form of Micro Battery , and steel substrate as the cathode and is protected. Thick zinc coating, fine crystalline, uniform and non-porous, corrosion resistance is good. It mist slowly in acid, alkali and other corrosive, which can effectively protect the steel substrate, and after chromate passivation to form white, color, military green, etc.nice, has a certain decorative.This paper studies Zn electroplating and subsequent passivation of galvanized the various process methods, and obtained a variety of passive film properties through Test and Evaluation ,to find a more suitable method of application process.The composition of the zinc coating microcosmic appearance and structure, corrosion production and the structure of passivation film and components have been analyzed and researched by means of adopting XRD, Glow Discharge Optical Emission Spectrometry(GDA-750), SEM(HitachiS-570) and Multifuctional Electronic Energy Spectrum(ESCALAB MK-Ⅱ).The property of the zinc film and the passivation film have been researched by the electrochemis