高分子溶液与胶体相转变的研究-化学物理专业论文.docxVIP

中国科学技术大学硕士学位论文 中国科学技术大学硕士学位论文 摘要 结晶共存；在体积分数45％与55％之间体系开始向玻璃态转变；当体积分数大 于55％时，体系转变为玻璃态。同样我们观察到MMA．CO．SA胶体粒子水溶液从 体积分数约小于30％开始有部分结晶出现；在体积分数35％与50％之间发生玻 璃化转变。 中国科学技术大学硕士学位论文 中国科学技术大学硕士学位论文 摘要 Ab stract The thesis deals with the phase transitions of N-isopropycrylamide ·。CO‘‘acrylic acid(NIPAM··CO·-AA)solution and the glass transitions of poly(styrene—CO—Sodium sulfonic styrene)(St—CO—SSS)as well as poly(Methyl Methacrylate—CO-Sodium Acrylic)(MMA—CO—SA)colloids． Firstly,we synthesized a series of random and segmented copolymers NIPAM—CO—AA．The LCST behavior of these copolymers in water was investigated with ultrasensitive microcalorimetry(US—DSC)by changing AA percentage，pH and ionic strength．We found that increasing pH of the solution will increase the exclusion between PAA fractions，SO the aggregation of NIPAM segments becomes difficult and consequently the LCST of the solutions increase．Addition of calcium ions into the solutions leads PAA chains to aggregate and lose water,SO the PNIPAM chains tum back to flexible and easy to aggregate and consequently the LCST of the solutions decreases．． Secondly,we synthesized a series of charged colloid particles and investigated the behavior of their concentrated aqueous solutions with the volume fraction from 5％to 60％using Internal Friction and Small Angle Light Scattering(SALS)．The intemal friction of the solution of St—CO-SSS colloids almost does not change at矽35％．In the range ．3． 中国科学技术大学硕士学位论文 中国科学技术大学硕士学位论文 摘要 3 5％^V45％the internal friction gradually increase and sharply increase at 445％．In SALS measurements the light scattering intensity increase along