高密度聚乙烯超高分子量聚乙烯共混体系动态流变学行为分析-高分子化学与物理专业论文.docxVIP

湘潭大学硕士论文高密度聚乙烯/ 湘潭大学硕士论文 高密度聚乙烯/超高分子量聚乙烯共混体系流变学行为研究 II II Abstract Polymer dynamics rheology is an effective method to study the relation of the evolution of its morphology and the rheological behavior, especially for multi-phase polymer system. In recent years, many study focused on the dynamic rheological properties of polyolefins (mainly polyethylene) blends. Mostly concentrated in the relation of thermal rheological behavior of blends and the phase behavior. It was lack necessary research to the relation of the evolution of its morphology and the rheological behavior in the processing. In this article, high-density polyethylene/ultrahigh molecular weight polyethylene (HDPE/UHMWPE), high density polyethylene/ultrahigh molecular weight polyethylene/calcium carbonate (HDPE/UHMWPE/CaCO3) blends was intended to take as a model. The influence of the processing parameters, including the processing temperature, screw shear rate, filler content, on the dynamic rheological behavior of the blends has been investigated. On this basis, the evolution of morphological structure on the system has been extrapolated. Study showed that for HDPE/UHMWPE blends (90/10wt%), the change of processing temperature or screw shear rate maked the dynamic rheological behavior of this system obviously transform. The results showed that the dispersion of UHMWPE improved with the increase of screw speed. The composite melts behaved various dynamic rheological behaviors. The storage moduli (G), loss moduli (G), zero shear viscosity (η0) of the HDPE/UHMWPE composite melts increased obviously at low frequency region, while the transition point of the viscoelasticity moved to low frequence region. Due to the dispersion improvement of UHMWPE, the initial crystallization temperature of HDPE/UHMWPE composites shifted to high temperature and the isothermal crystallization process was accelerated. The morphology of nascent UHMWPE powder was examined by scanning electronic microscopy (SEM). A morphology m