微波辐射对政烯和醇加成反应影晌.PDFVIP

第 27 卷第 2 期 南京林业大学学报(自然科学版) Vo 1. 27 , No.2 2003 年 3 月 Journal of Nanjing Forestry University( Natural Sciences Edition) Mar. , 2003 微波辐射对政烯与醇加成反应的影晌 欧文华，林中祥 (南京林业大学化学工程学院，江苏 南京 210037) 摘要:将微波辐射应用到政烯与醇加成反应中以提高其反应速率。笔者研究了微波辐射下 用对甲苯磺酸作催化剂时政烯与醇在密闭反应罐中的反应，探讨了微波功率、辐射时间及醇的 种类对反应的影响，并与普通加热条件下的反应进行比较。结果表明，政烯与丙醇在 700 W 功率的微波辐射下反应 30 min，异龙脑基丙隘的含量达 59.0% ，微波辐射下，政烯与醇加成反 应的速率大大提高;增大微波辐射功率，反应速率加快;空间位阻大的醉不利于反应的进行。 关键词:微波辐射;政烯;丙醇;异龙脑基曲直 文献标i只码:A 中图分类号 TQ655 文章编号: 1000- 2006(2003)02- 0037- 03 The Effect of Microwave Irradiations on the Reaction of Camphene with Alcohols OU Wen-hua ,LlN Zhong- xiang (College of Chemical Engineering Nanjing For臼try University , Nanjing 210037 , China) Abstract: A ci企catalyzed additional reactions of camphene w ith alcohols were investigated in the airtight pot reactor heated by microwaves in order to reduce the reaction time in the conventional heating conditions. The additional reaction was catalyzed with p-toluenesulfonic acid. The results indicated that microwave irra- diation could enhance greatly the rate of these reactions compared w ith conventional heating conditions. R e- action times were reduced from 15- 30 h using conventional conditions , to 30 min by microwave dielectric heating. Content of isobornyl propyl ether in the reactant was 59 .0% using microwave dielectric heating. While the branches of alcohols decreased the reaction rate because of the spatial obstruct. The methodology simplified the procedure and overcame the draw backs resulting from the long reaction times required under conventional heating cond