聚氨酯系汽车车底可防石击涂料的研究.docx

国防科学技术大学研究生院学位论文1L 国防科学技术大学研究生院学位论文 1L ]i宣iiii宣宣i置i宣iiiii置iiiiiiiiii宣iiiii酋iiiii宣iiiiiiii葺 Abstract The synthetic conditions of polyurethane elastomer fl uE)were optimized via Og吐lO 删design using half-prepolymerization．PU coating was modified by nanopartieles． The effects of nano-CaC03 on the mechanical properties and corresponding dynamic mechanical properties we∞studied．The properties of PU coating WeIe reinforced via Mding pigments and fillers with different structures．Surfacefects of the coating film were solved by various additives．Finally,Higher-class PU stone chip-resistant underbody coating was prepmd，with wider temperature瑚删驴of resultful damping and higher loss tangenL Firstly,the preparing processes of PUE were investigated．A liquefaeient MDI and polytetrahydrofuran(PTMG)we∞used as the starting materials,and 1,4-butanediol 0300) was used as chain extender．The optimal synthetic conditions of PUE were determined as follows：PTMG：MDI=4：6(mass ratio)，pouring once as charging method，T=85。C，t=2—3h, -NCO％=6．5％(ultimate)，R=1．15．Under this condition,properties of PUE were shown as follows：tensible strength of 4．67MPa,tear strength of 18．92kN／m,shore A hardness of 70， bn期ken elongation of 484．28％．Temperature range of resultful damping(tanl$O．25)was in the range of5～105℃，and ta】n6Il麟was 0．35． Secondly,PU ooatillg was modified by adding nano-CaC03 and the optimal disperse conditions Were obtained．When ingredient B of PU coating was used as dispersion medium,the best adding amount of nano—CaC03 in the range of 6～8wt％was obtained by the mixed dispersion method Coall mill 6h after ultrasonic dispersion 40min)．PU coating with nano-CaC03 showed higher performance than that of coming without nano-CaC03， and its tensile strength(5．33MPa)Was improved by 14．1％，tear strength(24．82kN／m)was raised by 3 1．2％，shore A hardness(74)was enhanced by 5．8％，elongation at break (422．98％)Was decreased a little．Temperature range of resultful damping(tanS0．25)Was in the range 0f_4¨120C which wa