基于多离子传输的混凝土细微观尺度多相数值模拟-硅酸盐学报.PDFVIP

第 46 卷第 8 期 硅 酸 盐 学 报 Vol. 46 ，No. 8 2 0 1 8 年 8 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY August ，2018 DOI ：10.14062/j.issn.0454-5648.2018.08.05 基于多离子传输的混凝土细微观尺度多相数值模拟 刘清风 (上海交通大学海洋工程国家重点实验室，上海 200240 ；高新船舶与深海开发装备协同创新中心，上海 200240) 摘 要：基于严格的 Gaussian 静电理论和对多相结构的参数控制，考虑多种离子间电化学耦合效应和骨料、界面过渡区的不 同形状及体积分数，在细微观尺度下建立多离子传输多相数值模型。通过求解质量守恒方程和 Poisson 方程，探明多离子的 时空分布规律。综合考虑外加电场、离子间相互作用、混凝土的各向异性、骨料-砂浆界面过渡区和离子吸附结合效应等因素 的影响，揭示了多离子传输与单一离子传输间的差异，以及多种曲折度效应之间的增益效果和影响程度。 关键词：多离子；多相模型；混凝土；氯离子；骨料形状；电化学耦合；“双多”模型 中图分类号：TU528 文献标志码：A 文章编号：0454–5648(2018)08–1074–07 网络出版时间：2018–05–24 Multi-Phase Modelling of Concrete at Meso-micro Scale Based on Multi-species Transport LIU Qingfeng (State Key Laboratory of Ocean Engineering, Shanghai Jiao Tong University, Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240, China) Abstract: A series of ‘double-multi’ models were developed in a meso-micro scale, in which the electro-coupling phenomenon of multi-species as well as various shapes and volume fractions of aggregates and ITZs was considered, based on the institutive electrochemistry law and parameter control of multi phases numerical modeling method. The spatial-temporal distribution characteristics of multi-component ionic transport were obtained by solving both the mass conservation equation and the Poisson equation. Through a comparatively overall study by considering a set of important influencing factors including external electric field, interactions between different species, heterogeneous nature of concrete, ITZ and binding effect,