加州大学伯克利分校有机化学第八章.pptVIP

? University of California ? Univesity of California Structure Hydrophobic-Hydrophilic Alkoxides RO Synthesis of Alcohols R-OH Retrosynthetic Analysis Roadmaps Ethanol Chapter 8: Alcohols R OH O H H O CH3 CH3 δ+ O H CH3 δ+ δ+ δ+ δ+ δ+ δ-- δ-- δ-- Water Alcohol Ether 1. Find the longest chain containing the –OH function: alkane ? alkanol. Note: This may not be the longest chain in the molecule! 2. Number such as to give HO-C lowest # 3. Other rules same as in alkanes 4,4-Dimethyl-1-nonanol 5-Bromo-3-propyl- 2-heptanol OH OH Br 1 2 3 4 5 6 7 8 9 1 2 3 4 5 6 Names 7 OH OH CH3 HO Cyclohexano