兖州煤气化半焦表面官能团特征试验研究-中国电机工程学报.PDF

第 30 卷 第 5 期 中 国 电 机 工 程 学 报 Vol.30 No.5 Feb.15, 2010 2010 年 2 月 15 日 Proceedings of the CSEE ©2010 Chin.Soc.for Elec.Eng. 17 0258-8013 (2010) 05-0017-06 TK 16 A 470 10 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 兖州煤气化半焦表面官能团特征试验研究 石金明，孙路石，向军，胡松，赵清森，苏胜，许凯，卢腾飞 (煤燃烧国家重点实验室(华中科技大学) ，湖北省 武汉市 430074) Experimental Study on Surface Functional Groups Characteristics of Yanzhou Semi-cokes of Gasification SHI Jin-ming, SUN Lu-shi, XIANG Jun, HU Song, ZHAO Qing-sen, SU Sheng, XU Kai, LU Teng-fei (State Key Laboratory of Coal Combustion (Huazhong University of Science and Technology), Wuhan 430074, Hubei Province, China) ABSTRACT: In order to reveal the changing rule of coal 始脂肪结构首先脱落，当温度较高时芳环才开始开链成脂肪 structure during coal gasification, the Yanzhou semi-cokes 结构并逐渐脱落；CO2参与气化反应，介入酚、醚、醇、酯 were made in tube furnace at 300~1 000 ℃, and the infrared 的C ＝O基官能团中，影响气化半焦的富总氧度。 spectrums were monitored by Fourier transform infrared 关键词：煤表面结构；脂肪结构；芳环结构；制焦温度；傅 spectroscopy (FTIR) at different gasification conditions, to 里叶变换红外光谱法 analyze the surface functional groups of Yanzhou coal. It was found that limited aliphatic structure in coal lead to small 0 引言 hydrocarbon capacity during coal gasification at low 煤作为宝贵的自然资源，其结构复杂，人们对 temperature, but the synergy of aromatic structure cracking and condensation could increase the hydrogen-enriched degree of 其研究和认