《N-乙酸乙酯吡-啶基氯盐离子液体的合成及对苎麻织物改性的研究》-毕业论文.docVIP

毕业设计(论文) 课题名称 N-乙酸乙酯吡啶基氯盐离子液体的合成 及对苎麻织物改性的研究 专业名称 轻化工程 学生姓名 学 号 指导教师 南京工业大学食品与轻工学院 N-乙酸乙酯吡啶基氯盐离子液体的合成 及对苎麻织物改性的研究 摘要 本文合成N-乙酸乙酯吡啶基氯盐离子液体，并以之作为改性剂，考察其对苎麻织物的改性，通过染色实验探讨其在不同温度下以及处理不同时间后苎麻织物的上染性能，并采用SEM、DSC-TG分析方法对改性后麻织物的形态及热行为进行表征。 结果表明：用N-乙酸乙酯吡啶基氯盐离子液体对苎麻织物改性后，可降低纤维的结晶度，增加纤维的无定型区，上染速率和上染率得到显著提高，其手感、刺痒感和易脆性也得到了改善。最佳工艺条件：离子液体处理温度80℃，处理时间为20min，在这种工艺条件下的麻织物强力保留率较高；升高温度，延长处理时间，麻织物强力下降明显。 关键词：离子液体；苎麻织物；改性；染色 Synthesis of N- ethyl acetate pyridine chlorine salt ionic liquid and modification on ramie fabric Abstract This paper synthesized the N- ethyl acetate pyridine chlorine salt ionic liquid, and the ionic liquid was used for modifier of ramie fabric. We studied the effects of modification time and temperature on dyeing properties of modified ramie fabrics. The surface morphology and thermal performance of ramie fabric was observed by SEM and DSC-TG. The results showed that after modified by N- ethyl acetate pyridine chlorine salt ionic liquid, the crystallinity of ramie fabric decreased, dyeing rate and dye-uptake increased remarkable. The shortcomings of ramie fabrics such as handle, prickle sensation and breakage were improved also. The optimum condition of modification is: temperature 80℃; time 20min. The ramie fabrics tensile breaking strengths was acceptable under this condition; The ramie fabrics tensile breaking strengths decreased obviously when elevated temperature. Keyword：Ionic liquid; ramie fabric; modification; Dyeing 目录 TOC \o 1-4 \h \z \u HYPERLINK \l _Toc264053962 摘要 Ⅰ HYPERLINK \l _Toc264053963 Abstract Ⅱ HYPERLINK \l _Toc264053964 第一章 前言 PAGEREF _Toc264053964 \h 1 HYPERLINK \l _Toc264053965 1.1 离子液体概述 PAGEREF _Toc264053965 \h 1 HYPERLINK \l _Toc264053966 1.2 离子液体的发展史 PAGEREF _Toc264053966 \h 2 HYPERLINK \l _Toc264053967 1.3 离子液体的组成和分类 PAGEREF _Toc264053967 \h 3 HYPERLINK \l _Toc264053968 1.3